SILICON-COMPOUNDS WITH STRONG INTRAMOLECULAR STERIC INTERACTIONS .53. CRYSTAL-STRUCTURE OF 2,2-DI-TERT-BUTYL-3-CYCLOHEXYL-4,5-DIPHENYL-1-OXA-2-SILA-3-AZA-4-CYCLOPENTENE

被引：1

作者：

PETERS, K ^{[1
]}

PETERS, EM ^{[1
]}

VONSCHNERING, HG ^{[1
]}

PIEL, H ^{[1
]}

WEIDENBRUCH, M ^{[1
]}

机构：

[1] FACHBEREICH CHEM, D-26111 OLDENBURG, GERMANY

来源：

ZEITSCHRIFT FUR KRISTALLOGRAPHIE | 1994年 / 209卷 / 07期

关键词：

CRYSTAL STRUCTURE; ALPHA-KETOIMINES; SILYLENE ADDITION;

D O I：

10.1524/zkri.1994.209.7.611

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound was synthesized by photolysis of hexa-tert-butylcyclotrisilane in the presence of N-cyclohexyl-2,3-diphenyl-alpha-ketoimine. It crystallizes from n-pentane monoclinically in the space group P2(1)/a with a = 1823.2(1) pm, b = 1041.1(1) pm, c = 1366.3(1) pm and beta = 96.52(1)-degrees

引用

页码：611 / 612

页数：2

共 5 条

[1] SILICON-COMPOUNDS WITH STRONG INTRAMOLECULAR, STERIC INTERACTIONS .16. HEXA-TERT-BUTYLCYCLOTRISILANE, A STRAINED MOLECULE WITH UNUSUALLY LONG SI-SI AND SI-C BONDS
SCHAFER, A
WEIDENBRUCH, M
PETERS, K
VONSCHNERING, HG
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1984, 23 (04): : 302 - 303
[2] SCHAFER A, 1984, ANGEW CHEM, V96, P311
[3] WEIDENBRUCH M, 1991, FRONTIERS OF ORGANOSILICON CHEMISTRY, P122
[4] SILICON-COMPOUNDS WITH STRONG INTRAMOLECULAR STERIC INTERACTIONS .50. REACTIONS OF SILYLENES AND DISILENES WITH 2,2'-BIPYRIDYL, PYRIDINE-2-ALDIMINES AND ALPHA-KETOIMINES - CYCLOADDITIONS VERSUS C-H INSERTION
WEIDENBRUCH, M
PIEL, H
LESCH, A
PETERS, K
VONSCHNERING, HG
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 454 (1-2) : 35 - 43
[5] WEIDENBRUCH M, 1992, CHEM INORGANIC RING, V14, P51

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