Crystal structure of tricarbonyl(N-diphenyl-phosphanyl-N,N '-diisopropyl-P-phenylphosphonous diamide-kappa P-2,P ')cobalt(I)tetracarbonylcobaltate(-I) toluene 0.25-solvate

被引：1

作者：

Dura, Laura ^{[1
]}

Spannenberg, Anke ^{[1
]}

Beweries, Torsten ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

crystal structure; cobalt; phosphine ligand; metallacycle;

D O I：

10.1107/S1600536814024908

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The asymmetric unit of the title compound, [Co(C24H30N2P2)(CO)(3)][Co(CO)(4)]-0.25C(7)H(8), consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene molecule disordered about an inversion centre. In the cations, a Co/P/N/P four-membered slightly bent metallacycle is the key structural element. The pendant NH group is not coordinated to the Co-I atom, which displays a distorted trigonal-bipyramidal coordination geometry. Weak interionic hydrogen bonds are observed between the NH groups and a carbonyl group of the tetrahedral [Co(CO)(4)](-) anions.

引用

页码：533 / +

页数：17

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