Crystal structure of tricarbonyl(N-diphenyl-phosphanyl-N,N '-diisopropyl-P-phenylphosphonous diamide-kappa P-2,P ')cobalt(I)tetracarbonylcobaltate(-I) toluene 0.25-solvate

被引：2
|
作者：
Dura, Laura [1 ]
Spannenberg, Anke [1 ]
Beweries, Torsten [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
crystal structure; cobalt; phosphine ligand; metallacycle;
D O I：
10.1107/S1600536814024908
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [Co(C24H30N2P2)(CO)(3)][Co(CO)(4)]-0.25C(7)H(8), consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene molecule disordered about an inversion centre. In the cations, a Co/P/N/P four-membered slightly bent metallacycle is the key structural element. The pendant NH group is not coordinated to the Co-I atom, which displays a distorted trigonal-bipyramidal coordination geometry. Weak interionic hydrogen bonds are observed between the NH groups and a carbonyl group of the tetrahedral [Co(CO)(4)](-) anions.
引用
收藏
页码：533 / +
页数：17
相关论文
共 20 条
  • [1] Crystal structure of [1,3-bis(diphenylphosphanyl)propane-kappa P-2, P '](N, N '-dimethylthiourea-kappa S)(thiocyanato-kappa N) copper(I)
    Wattanakanjana, Yupa
    Nimthong-Roldan, Arunpatcha
    Ratthiwan, Janejira
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M61 - +
  • [2] Crystal structure of tris[mu(2)-bis(diphenyl-phosphanyl)methane-kappa P-2:P']di-mu(3)- bromido-trisilver(I) bromide-N,N-phenylthiourea (1/1)
    Nimthong-Roldan, Arunpatcha
    Wattanakanjana, Yupa
    Rodkeaw, Jintana
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M89 - U131
  • [3] Crystal structure of bis[mu-1,2-bis(diphenylphosphanyl)ethane-kappa P-2:P ']bis[(N,N '-diethylthiourea-kappa S)iodidocopper(I)]
    Khongsichan, Ladawan
    Nimthong-Roldan, Arunpatcha
    Pakawatchai, Chaveng
    Wongnawa, Sumpun
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M154 - +
  • [4] Crystal structure of an unknown tetrahydrofuran solvate of tetrakis(mu(3)-cyanato-kappa N-3:N:N)tetrakis-[(triphenylphosphane-kappa P)silver(I)]
    Frenzel, Peter
    Schaarschmidt, Dieter
    Jakob, Alexander
    Lang, Heinrich
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 1262 - +
  • [5] Crystal structure of bis[tetrakis(triphenylphosphane-kappa P)silver(I)] (nitrilotriacetato-kappa N-4,O,O ',O '')(triphenylphosphane-kappa P)argentate(I) with an unknown amount of methanol as solvate
    Noll, Julian
    Korb, Marcus
    Lang, Heinrich
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 318 - +
  • [6] Crystal structure of tris[mu(2)-bis(diphenylphosphanyl)methane-kappa P-2:P ']di-mu(3)-iodidotrisilver(I) iodide-N-phenylthiourea (1/1)
    Wattanakanjana, Yupa
    Nimthong-Roldan, Arunpatcha
    Palavat, Suthida
    Puetpaiboon, Walailak
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M187 - U89
  • [7] Crystal structure of bis[mu-1,4-bis(diphenylphosphanyl)butane-kappa P-2:P ']bis[(3,4,7,8-tetramethyl-1 10-phenanthroline-kappa N-2,N ')copper(I)] bis(hexafluoridophosphate) dichloromethane disolvate
    Nishikawa, Michihiro
    Mutsuura, Kotaro
    Tsubomura, Taro
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1554 - +
  • [8] Crystal structure of (mu-N-allylthiourea-kappa(2) S: S) bis[mu-bis(diphenylphosphanyl) methane-kappa(2) P: P']bis[bromidocopper(I)] acetonitrile disolvate
    Hemman, Mareeya
    Pakawatchai, Chaveng
    Boonmak, Jaursup
    Youngme, Sujittra
    Saithong, Saowanit
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 1081 - +
  • [9] [N,N-Bis(2-hydroxyethyl)dithiocarbamato-kappa S-2,S ']bis(triphenylphosphane-kappa P)copper(I) chloroform monosolvate: crystal structure, Hirshfeld surface analysis and solution NMR measurements
    Tan, Sang Loon
    Yeo, Chien Ing
    Heard, Peter J.
    Akien, Geoffrey R.
    Halcovitch, Nathan R.
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1799 - +
  • [10] A monoclinic polymorph of [(Z)-N-(3-chlorophenyl)-O-methylthiocarbamato-kappa S](triphenylphosphane-kappa P)gold(I): crystal structure and Hirshfeld surface analysis
    Yeo, Chien Ing
    Tan, Sang Loon
    Tiekink, Edward R. T.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1068 - +
12