Crystal structure of tricarbonyl(N-diphenyl-phosphanyl-N,N '-diisopropyl-P-phenylphosphonous diamide-kappa P-2,P ')cobalt(I)tetracarbonylcobaltate(-I) toluene 0.25-solvate

被引：1
|
作者：
Dura, Laura [1 ]
Spannenberg, Anke [1 ]
Beweries, Torsten [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
crystal structure; cobalt; phosphine ligand; metallacycle;
D O I：
10.1107/S1600536814024908
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title compound, [Co(C24H30N2P2)(CO)(3)][Co(CO)(4)]-0.25C(7)H(8), consists of two crystallographically independent cations with similar conformations, two anions, and one-half of a toluene molecule disordered about an inversion centre. In the cations, a Co/P/N/P four-membered slightly bent metallacycle is the key structural element. The pendant NH group is not coordinated to the Co-I atom, which displays a distorted trigonal-bipyramidal coordination geometry. Weak interionic hydrogen bonds are observed between the NH groups and a carbonyl group of the tetrahedral [Co(CO)(4)](-) anions.
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页码：533 / +
页数：17
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