1-[(1S, 6R, 7S, 9R)-8,8-Dibromo-5,5,9-tri-methyltricyclo[4.4.0.1(7,9)]decan-1-yl]-ethanone

被引：1

作者：

Zaki, Mohamed ^{[1
]}

Benharref, Ahmed ^{[1
]}

El Ammari, Lahcen ^{[2
]}

Saadi, Mohamed ^{[2
]}

Berraho, Moha ^{[1
]}

机构：

[1] Fac Sci, Lab Chim Biomol Subst Naturelles & React, URAC 16, BP 2390 Bd My Abdellah, Marrakech 40000, Morocco

[2] Univ Mohammed V Agdal, Fac Sci, Lab Chim Solide Appliquee, Rabat, Morocco

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

关键词：

D O I：

10.1107/S1600536814005431

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, C16H24Br2O, was synthesized by three steps from beta-himachalene (3,5,5,9-tetramethyl-2,4a, 5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from essential oil of the Atlas cedar cedrus atlantica. The asymmetric unit contains two independent molecules with almost identical conformations. Each molecule is built up from two fused six-membered rings, one having a chair conformation and the other a boat conformation, and an additional three-membered ring arising from the reaction of himachalene with dibromocarbene. In the crystal, there are no significant intermolecular interactions present. The absolute structure of the title compound was confirmed by resonance scattering.

引用

页码：O444 / +

页数：10

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