HYDROGEN-BOND COOPERATIVITY AND FREE-VOLUME EFFECTS ON NORMAL AND SUPERCOOLED WATER SELF-DIFFUSION

被引:9
|
作者
LAMANNA, R [1 ]
CANNISTRARO, S [1 ]
机构
[1] UNIV TUSCIA, DIPARTIMENTO SCI AMBIENTALI, SEZ CHIM & FIS, VITERBO, ITALY
来源
PHYSICAL REVIEW A | 1992年 / 46卷 / 12期
关键词
D O I
10.1103/PhysRevA.46.R7367
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
The interpretation of the experimental self-diffusion data on normal and supercooled water has been revisited in the light of both the recently reported evidence for a temperature-dependent H-bond cooperativity and the free-volume fluctuations within the water percolative patches. The proposed model, which is consistent with the presence of a continuity of states between liquid and solid phases, was found to fit the NMR experimental data to an accuracy comparable to that obtained by a power law.
引用
收藏
页码:R7367 / R7370
页数:4
相关论文
共 50 条
  • [41] POLYMERIC SOLID ELECTROLYTES - DYNAMIC BOND PERCOLATION AND FREE-VOLUME MODELS FOR DIFFUSION
    DRUGER, SD
    RATNER, MA
    NITZAN, A
    SOLID STATE IONICS, 1983, 9-10 (DEC) : 1115 - 1120
  • [42] Simultaneous free-volume modeling of the self-diffusion coefficient and dynamic viscosity at high pressure -: art. no. 031203
    Boned, C
    Allal, A
    Baylaucq, A
    Zéberg-Mikkelsen, CK
    Bessieres, D
    Quiñones-Cisneros, SE
    PHYSICAL REVIEW E, 2004, 69 (03): : 031203 - 1
  • [43] INCREASED SELF-DIFFUSION OF BRAIN WATER IN NORMAL AGING
    GIDEON, P
    THOMSEN, C
    HENRIKSEN, O
    JMRI-JOURNAL OF MAGNETIC RESONANCE IMAGING, 1994, 4 (02): : 185 - 188
  • [44] Viscosity and self-diffusion of supercooled and stretched water from molecular dynamics simulations
    de Hijes, Pablo Montero
    Sanz, Eduardo
    Joly, Laurent
    Valeriani, Chantal
    Caupin, Frederic
    JOURNAL OF CHEMICAL PHYSICS, 2018, 149 (09):
  • [45] THE PRESSURE-DEPENDENCE OF SELF-DIFFUSION IN SUPERCOOLED LIGHT AND HEAVY-WATER
    PRIELMEIER, FX
    LANG, EW
    SPEEDY, RJ
    LUDEMANN, HD
    BERICHTE DER BUNSEN-GESELLSCHAFT-PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 1988, 92 (10): : 1111 - 1117
  • [46] Experimental tests of free-volume tracer diffusion in water and other solvents
    Spiegel, Daniel R.
    Kollie, Paulses C.
    Van Tilburg, Scott J.
    JOURNAL OF CHEMICAL PHYSICS, 2014, 140 (10):
  • [47] Water Diffusion Proceeds via a Hydrogen-Bond Jump Exchange Mechanism
    Gomez, Axel
    Piskulich, Zeke A.
    Thompson, Ward H.
    Laage, Damien
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2022, 13 (21): : 4660 - 4666
  • [48] Diffusion of liquid n-alkanes:: Free-volume and density effects
    von Meerwall, E
    Beckman, S
    Jang, J
    Mattice, WL
    JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (10): : 4299 - 4304
  • [49] Nuclear Quantum Effects in Water Reorientation and Hydrogen-Bond Dynamics
    Wilkins, David M.
    Manolopoulos, David E.
    Pipolo, Silvio
    Laage, Damien
    Hynes, James T.
    JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2017, 8 (12): : 2602 - 2607
  • [50] EFFECTS OF FREE-VOLUME ON STRESS-RELAXATION WITH BOND BREAKING IN POLYMERIC MATERIALS
    BROSTOW, W
    TURNER, DP
    JOURNAL OF RHEOLOGY, 1986, 30 (04) : 767 - 780