MONOCYCLOPENTADIENYLMOLYBDENUM(III) CHEMISTRY

被引：31
作者：
POLI, R
机构：
[1] Department of Chemistry and Biochemistry, University of Maryland, Maryland, College Park
来源：
JOURNAL OF COORDINATION CHEMISTRY | 1993年 / 29卷 / 1-2期
关键词：
PARAMAGNETIC ORGANOMETALLIC COMPOUNDS; 4-LEGGED PIANO STOOL STRUCTURES; INTERMEDIATE OXIDATION STATE;
D O I：
10.1080/00958979308037131
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, structure, properties, and reactivity of complexes of Mo(III) containing one cyclopentadienyl or substituted cyclopentadienyl ring are reviewed. In particular, the electronic structure of mononuclear (radical) compounds and the synergistic stabilization through X -->pi Mo and Mo -->pi L interactions are discussed, as well as the effect of these interactions on the molecular structure and on the redox potentials of the compounds.
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页码：121 / 173
页数：53
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