MONOCYCLOPENTADIENYLMOLYBDENUM(III) CHEMISTRY

被引：31
作者：
POLI, R
机构：
[1] Department of Chemistry and Biochemistry, University of Maryland, Maryland, College Park
来源：
JOURNAL OF COORDINATION CHEMISTRY | 1993年 / 29卷 / 1-2期
关键词：
PARAMAGNETIC ORGANOMETALLIC COMPOUNDS; 4-LEGGED PIANO STOOL STRUCTURES; INTERMEDIATE OXIDATION STATE;
D O I：
10.1080/00958979308037131
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis, structure, properties, and reactivity of complexes of Mo(III) containing one cyclopentadienyl or substituted cyclopentadienyl ring are reviewed. In particular, the electronic structure of mononuclear (radical) compounds and the synergistic stabilization through X -->pi Mo and Mo -->pi L interactions are discussed, as well as the effect of these interactions on the molecular structure and on the redox potentials of the compounds.
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页码：121 / 173
页数：53
相关论文
共 73 条
[1]   4-LEGGED PIANO STOOL MOLYBDENUM(II) COMPOUNDS WITHOUT CARBONYL LIGANDS .1. SYNTHESIS, PROPERTIES, AND CHLORIDE SUBSTITUTION-REACTIONS OF (ETA-5-C5R5)MOCL(PME3)3 (R = H, ME) AND X-RAY CRYSTAL-STRUCTURE OF [CPMOCL(PME3)3]+PF6- [J].
ABUGIDEIRI, F ;
KELLAND, MA ;
POLI, R ;
RHEINGOLD, AL .
ORGANOMETALLICS, 1992, 11 (03) :1303-1311
[2]  
ABUGIDEIRI F, IN PRESS
[3]   ETA-3-ALLYL COMPLEXES OF MOLYBDENUM .4. PREPARATION AND CRYSTAL-STRUCTURES OF SOME SUBSTITUTED-CYCLOPENTADIENYL MOLYBDENUM ALLYL DERIVATIVES [J].
ANDELL, O ;
GODDARD, R ;
HOLLE, S ;
JOLLY, PW ;
KRUGER, C ;
TSAY, YH .
POLYHEDRON, 1989, 8 (02) :203-209
[4]   [CR(ETA-3-C3H5)2(ETA-5-C5H5)] - PREPARATION, STRUCTURE, AND REACTIONS [J].
ANGERMUND, K ;
DOHRING, A ;
JOLLY, PW ;
KRUGER, C ;
ROMAO, CC .
ORGANOMETALLICS, 1986, 5 (06) :1268-1269
[5]   ETA-3-ALLYL COMPLEXES OF TUNGSTEN .3. THE PREPARATION OF (ETA-5-C5H5)(ETA-3-C3H5)2(ETA-1-C3H5)W AND RELATED-COMPOUNDS [J].
AZEVEDO, MC ;
BROCK, TH ;
JOLLY, PW ;
RUFINSKA, A ;
SCHROTH, G .
POLYHEDRON, 1991, 10 (4-5) :459-462
[6]   CHARGE-TRANSFER SALTS FORMED FROM REDOX-ACTIVE CUBANE CLUSTER CATIONS (M4(ETA-C5H4R)4(MU-3-E)4)N+ (M = CR, FE OR MO E = S OR SE) AND VARIOUS ANIONS [J].
BAIRD, P ;
BANDY, JA ;
GREEN, MLH ;
HAMNETT, A ;
MARSEGLIA, E ;
OBERTELLI, DS ;
PROUT, K ;
QIN, JG .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (09) :2377-2393
[7]   EPR-SPECTRA OF (C5ME5)MOCL2(PME3)2 IN SOLUTION AND IN SINGLE-CRYSTALS OF (C5ME5)MOCL(PME3)2(N2) [J].
BAKER, RT ;
MORTON, JR ;
PRESTON, KF ;
WILLIAMS, AJ ;
LEPAGE, Y .
INORGANIC CHEMISTRY, 1991, 30 (01) :113-116
[8]  
BAKER RT, IN PRESS ORGANOMETAL
[9]   SYNTHESIS, CRYSTAL-STRUCTURES, AND BONDING OF THE MOLYBDENUM CUBANE COMPOUNDS [MO(MU-C5H4PRI)(MU-3-S)]4N+, WHERE N = 0, 1, AND 2 [J].
BANDY, JA ;
DAVIES, CE ;
GREEN, MLH ;
GREEN, JC ;
PROUT, K ;
RODGERS, DPS .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1983, (23) :1395-1397
[10]   REACTIONS OF METAL-COMPLEXES WITH STRAINED HETEROCYCLES .3. POLYNUCLEAR PI-CYCLOPENTADIENYL-SULFUR-MOLYBDENUM COMPLEXES FROM PROPYLENE SULFIDE AND PI-CYCLOPENTADIENYLCARBONYLMOLYBDENUM HYDRIDES [J].
BECK, W ;
DANZER, W ;
THIEL, G .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1973, 12 (07) :582-582
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