Crystal structure of bis(2,2 ': 6 ',2 ''-terpyridine- kappa N-3, N ', N '')nickel(II) dicyanidoaurate(I)

被引:1
作者
White, Frankie [1 ]
Sykora, Richard E. [1 ]
机构
[1] Univ S Alabama, Dept Chem, Mobile, AL 36688 USA
来源
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
基金
美国国家科学基金会;
关键词
crystal structure; terpyridine; aurophilic interaction; dicyanidoaurate;
D O I
10.1107/S1600536814024672
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title compound, [Ni(C15H11N3)(2)][Au(CN)(2)](2), is an ionic compound composed of bis(2,2 ': 6 ', 2 ''-terpyridine)nickel(II) dications and dicyanidoaurate(I) anions in a 1: 2 ratio. The two tridentate terpyridine ligands define the coordination of the Ni (2+) cation, resulting in a nearly octahedral coordination sphere, although there is not any imposed crystallographic symmetry about the Ni 2+ site. The two nearly linear dicyanidoaurate(I) anions [C-Au-C = 179.0 (2) and 178.2 (2)degrees] contain a short aurophilic interaction of 3.1017 (3) angstrom. The structure does not demonstrate any pi-pi stacking. Non-classical C-H center dot center dot center dot N interactions between the cations and anions build up a three-dimensional network.
引用
收藏
页码:519 / +
页数:10
相关论文
共 9 条
  • [1] [Anonymous], 2014, CRYSALIS PRO
  • [2] OLEX2: a complete structure solution, refinement and analysis program
    Dolomanov, Oleg V.
    Bourhis, Luc J.
    Gildea, Richard J.
    Howard, Judith A. K.
    Puschmann, Horst
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 : 339 - 341
  • [3] NITROGENOUS CHELATE COMPLEXES OF TRANSITION METALS .8. COMPLEXES OF NICKEL(II) WITH 2,2',2''-TERPYRIDINE
    HARRIS, CM
    LOCKYER, TN
    [J]. AUSTRALIAN JOURNAL OF CHEMISTRY, 1970, 23 (08) : 1703 - &
  • [4] Polymorphism of Zn[Au(CN)2]2 and its luminescent sensory response to NH3 vapor
    Katz, Michael J.
    Ramnial, Taramatee
    Yu, Hua-Zhong
    Leznoff, Daniel B.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) : 10662 - 10673
  • [5] The Use of Polarizable [AuX2(CN)2]- (X = Br, I) Building Blocks Toward the Formation of Birefringent Coordination Polymers
    Ovens, Jeffrey S.
    Geisheimer, Andrew R.
    Bokov, Alexei A.
    Ye, Zuo-Guang
    Leznoff, Daniel B.
    [J]. INORGANIC CHEMISTRY, 2010, 49 (20) : 9609 - 9616
  • [6] One- and two-dimensional polymerisation of homoleptic M(II)-complexes of 4′-(3-pyridyl)-2,2′;6′,2"-terpyridine in the solid state: A combined study by XRD, cyclic voltammetry, NMR and UV-Vis spectroscopies
    Pal, Amlan K.
    Laramee-Milette, Baptiste
    Hanan, Garry S.
    [J]. INORGANICA CHIMICA ACTA, 2014, 418 : 15 - 22
  • [7] 2,2′:6′,2"-Terpyridine metal complexes as building blocks for extended functional metallo-supramolecular assemblies and polymers
    Schubert, US
    Eschbaumer, C
    Andres, P
    Hofmeier, H
    Weidl, CH
    Herdtweck, E
    Dulkeith, E
    Morteani, A
    Hecker, NE
    Feldmann, J
    [J]. SYNTHETIC METALS, 2001, 121 (1-3) : 1249 - 1252
  • [8] A short history of SHELX
    Sheldrick, George M.
    [J]. ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2008, 64 : 112 - 122
  • [9] publCIF: software for editing, validating and formatting crystallographic information files
    Westrip, Simon P.
    [J]. JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2010, 43 : 920 - 925