Crystal structure of bis(2,2 ': 6 ',2 ''-terpyridine- kappa N-3, N ', N '')nickel(II) dicyanidoaurate(I)

被引：1

作者：

White, Frankie ^{[1
]}

Sykora, Richard E. ^{[1
]}

机构：

[1] Univ S Alabama, Dept Chem, Mobile, AL 36688 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷

基金：

美国国家科学基金会;

关键词：

crystal structure; terpyridine; aurophilic interaction; dicyanidoaurate;

D O I：

10.1107/S1600536814024672

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Ni(C15H11N3)(2)][Au(CN)(2)](2), is an ionic compound composed of bis(2,2 ': 6 ', 2 ''-terpyridine)nickel(II) dications and dicyanidoaurate(I) anions in a 1: 2 ratio. The two tridentate terpyridine ligands define the coordination of the Ni (2+) cation, resulting in a nearly octahedral coordination sphere, although there is not any imposed crystallographic symmetry about the Ni 2+ site. The two nearly linear dicyanidoaurate(I) anions [C-Au-C = 179.0 (2) and 178.2 (2)degrees] contain a short aurophilic interaction of 3.1017 (3) angstrom. The structure does not demonstrate any pi-pi stacking. Non-classical C-H center dot center dot center dot N interactions between the cations and anions build up a three-dimensional network.

引用

页码：519 / +

页数：10

共 50 条

[1] Crystal structure of dichlorido(2,2 ':6 ',2 ''-terpyridine-kappa N-3,N ',N '')zinc: a redetermination
Kong, Cheng-Cheng
Zhou, Jia Zheng
Yu, Jian-Hua
Li, Sheng-Li
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M382 - +
[2] Crystal structure of trichlorido(4 '-ferrocenyl-2,2 ': 6 ', 2 ''-terpyridine-kappa N-3, N ', N '')iridium(III) acetonitrile disolvate
Davaasuren, Bambar
Padhy, Harihara
Rothenberger, Alexander
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M69 - +
[3] Crystal structure of bis(2,2 '-bipyridine-kappa(2) N, N ')bis(thiocyanato-kappa N) manganese(II) 2,2 '-bipyridine monosolvate
Suckert, Stefan
Jess, Inke
Naether, Christian
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M3 - +
[4] Crystal structure of catena-poly[[ aqua( 2,2': 6',2''-terpyridine-kappa N-3,N',N'') cobalt(II)]-mu-cyanido-kappa N-2:C-[dicyanidoplatinum(II)]-mu-cyanido-kappa C-2:N]
White, Frankie
Sykora, Richard E.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M322 - +
[5] Crystal structure of bis(azido-kappa N)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-kappa N-2(2), N-3]nickel(II)
Laachir, Abdelhakim
Bentiss, Fouad
Guesmi, Salaheddine
Saadi, Mohamed
El Ammari, Lahcen
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M24 - U106
[6] Crystal structure of diaquabis(2-chloropyridine-kappa N)bis(thiocyanato-kappa N) nickel(II)
Suckert, Stefan
Jess, Inke
Naether, Christian
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 1492 - +
[7] Crystal structure of bis(azido-kappa N)bis[2,5-bis(pyridin-2-yl)-1,3,4-thiadiazole-kappa N-2(2),N-3]cobalt(II)
Laachir, Abdelhakim
Bentiss, Fouad
Guesmi, Salaheddine
Saadi, Mohamed
El Ammari, Lahcen
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 452 - +
[8] Crystal structure of mu-peroxido-kappa O-4(1),O-2:O-1',O-2-bis[nitrato-kappa O)-(2,2 ':6 ',2"-terpyridine-kappa N-3,N,N")dioxidouranium(VI)]
Kawasaki, Takeshi
Kitazawa, Takafumi
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : M122 - U180
[9] Crystal structure of bis(acetato-kappa O)diaqua(2,2 '-bipyridine-kappa N-2,N ')manganese(II)
Saravanan, Natarajan
Selvam, Parasuraman
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M326 - +
[10] Crystal structure of di-mu-benzato-kappa O-4:O' bis[aqua(benzato-kappa O)(benzato-kappa O-2,O')(2,2':6',2''-terpyridine-kappa N-3,N',N'')europium(III)]-benzoicacid (1/2)
White, Frankie
Sykora, Richard E.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2014, 70 : M328 - +

← 1 2 3 4 5 →