SYNTHESIS AND CHARACTERIZATION OF AMINO-ACID SCHIFF-BASE COMPLEXES OF NICKEL(II)

被引:45
|
作者
WANG, GB
CHANG, JC
机构
[1] UNIV NO IOWA,DEPT CHEM,CEDAR FALLS,IA 50614
[2] XIANYANG TEACHERS COLL,DEPT CHEM,XIANYANG,PEOPLES R CHINA
关键词
D O I
10.1080/00945719408001385
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A series of nickel(II) complexes of Schiff bases obtained by the condensation of 2-hydroxy-3-methylbenzaldehyde and 2,4-dihydroxybenzaldehyde with glycine, DL-alanine, DL-valine, DL-methionine, L-leucine, and DL-phenylalanine were synthesized and characterized by elemental analyses, molar electrical conductivities, magnetic moments, infrared spectra, and thermoanalyses. All the complexes were found to be non-electrolytes with the general empirical formula [NiL(H2O)2], where L is an amino acid Schiff base ligand. The probable structure of the complexes is suggested.
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页码:1091 / 1097
页数:7
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