Crystal structure of trans-dihydrido-bis[tris(dimethylamino)phosphane-kappa P]- platinum(II)

被引：0
|
作者：
Downs, Emma L. [1 ]
Zakharov, Lev N. [1 ]
Tyler, David R. [1 ]
机构：
[1] 1253 Univ Oregon, Dept Chem & Biochem, Eugene, OR 97403 USA
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
基金：
美国国家科学基金会;
关键词：
crystal structure; tris(dimethylamino)phosphane; platinum(II) complex; ligand-assisted hydration; nitrile hydration;
D O I：
10.1107/S2056989015004351
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The molecule of the title compound, [PtH2(C6H18N3P)(2)], has a centrosymmetric square-planar structure in which the Pt" atom is bonded to two H and two P atoms in a mutually trans configuration. The Pt-II atom sits on an inversion center and thus the asymmetric unit contains only half the molecule. The Pt-P and Pt-H distances are 2.2574 (10) and 1.49 (7) angstrom, respectively.
引用
收藏
页码：M83 / U84
页数：7
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