THE STAGED SYNTHESIS OF 2-METHYLIMIDAZOLE FROM ETHYLENEDIAMINE AND ACETIC-ACID IN THE PRESENCE OF A BIFUNCTIONAL ALUMINOPLATINUM CATALYST

被引：2

作者：

GITIS, KM

RAEVSKAYA, NI

ISAGULYANTS, GV

机构：

来源：

BULLETIN OF THE RUSSIAN ACADEMY OF SCIENCES-DIVISION OF CHEMICAL SCIENCE | 1992年 / 41卷 / 09期

关键词：

ALUMINOPLATINUM CATALYSTS; BIFUNCTIONAL CATALYSIS; ALKYLIMIDAZOLES; 2-METHYLIMIDAZOLE;

D O I：

10.1007/BF00863570

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An investigation has been conducted into the staged synthesis of 2-methylimidazole from ethylenediamine and acetic acid in the presence of a bifunctional aluminoplatinum catalyst. It has been shown that the formation stage of 2-methylimidazoline occurs more quickly on gamma-Al2O3 than its dehydrogenation on the Pt centers. From a comparison of the processes of dehydrogenation of 2-methylimidazoline in the molten phase and in aqueous solution it follows that the water eliminated in the imidazoline formation stage could cause the decrease in activity during the dehydrogenation on the Pt centers. The structures of the secondary and intermediate products have been established for each stage of the process and their formation routes are discussed.

引用

页码：1551 / 1554

页数：4