THE ELECTROCHEMICAL FLUORINATION OF NITROGEN-CONTAINING CARBOXYLIC-ACIDS - FLUORINATION OF METHYL-ESTERS OF 3-DIALKYLAMINO PROPIONIC ACIDS

被引：23

作者：

ABE, T ^{[1
]}

HAYASHI, E ^{[1
]}

FUKAYA, H ^{[1
]}

HAYAKAWA, Y ^{[1
]}

BABA, H ^{[1
]}

ISHIKAWA, S ^{[1
]}

ASAHINO, K ^{[1
]}

机构：

[1] AICHI INST TECHNOL,DEPT IND CHEM,TOYOTA 47003,JAPAN

来源：

JOURNAL OF FLUORINE CHEMISTRY | 1992年 / 57卷 / 1-3期

关键词：

D O I：

10.1016/S0022-1139(00)82821-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Six methyl esters of 3-dialkylamino-substituted propionic acids were subjected to electrochemical fluorination to give the corresponding perfluoroacid fluorides. The following dialkylamino substituents were investigated: diethylamino, di-n-propylamino, di-n-butylamino, pyrrolidino, morpholino and piperidino groups. These perfluoroacid fluorides, which were obtained in fair yields, are considered to be prospective key precursors for preparing soft-type (degradable) fluorochemicals. The salts show a considerable lowering of surface tension in aqueous solution. The physical properties of all the perfluoroacid fluorides obtained are reported, together with their spectroscopic data (F-19 NMR, mass and IR spectra).

引用

页码：101 / 111

页数：11

共 16 条

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