SYNTHESIS, STRUCTURE, ELECTRIC, AND MAGNETIC-PROPERTIES OF CANIN

被引：91
|
作者：
CHERN, MY
DISALVO, FJ
机构：
[1] Department of Chemistry, Cornell University, Ithaca
来源：
JOURNAL OF SOLID STATE CHEMISTRY | 1990年 / 88卷 / 02期
关键词：
D O I：
10.1016/0022-4596(90)90242-P
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
We report the synthesis and physical properties of the new ternary nitride CaNiN, prepared by the reaction of Ca3N2 and Ni in N2 gas at 1000°C. The structure, determined by the method of X-ray powder diffraction, is tetragonal ( P42 mmc) with a = 3.5809(2) Å, c = 7.0096(3) Å, and Z = 2. While the structure is a simple but uncommone one, with all atoms occupying fixed special positions, it features interesting-NiNNiN-linear chains. Conductivity and magnetic measurements show that CaNiN is metallic and paramagnetic. © 1990.
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页码：459 / 464
页数：6
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