SYNTHESIS, STRUCTURE, ELECTRIC, AND MAGNETIC-PROPERTIES OF CANIN

被引：91

作者：

CHERN, MY

DISALVO, FJ

机构：

[1] Department of Chemistry, Cornell University, Ithaca

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 1990年 / 88卷 / 02期

关键词：

D O I：

10.1016/0022-4596(90)90242-P

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

We report the synthesis and physical properties of the new ternary nitride CaNiN, prepared by the reaction of Ca3N2 and Ni in N2 gas at 1000°C. The structure, determined by the method of X-ray powder diffraction, is tetragonal ( P42 mmc) with a = 3.5809(2) Å, c = 7.0096(3) Å, and Z = 2. While the structure is a simple but uncommone one, with all atoms occupying fixed special positions, it features interesting-NiNNiN-linear chains. Conductivity and magnetic measurements show that CaNiN is metallic and paramagnetic. © 1990.

引用

页码：459 / 464

页数：6

共 21 条

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[2]

CORDIER G, 1989, ANGEW CHEM INT EDIT, V2, P28

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