X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF ELECTRODE SURFACES USING A NEW CONTROLLED TRANSFER TECHNIQUE .2. RESULTS FOR A MOLYBDENUM ELECTRODE AND THE CURVE FITTING PROCEDURE

被引：190

作者：

ANSELL, RO ^{[1
]}

DICKINSON, T ^{[1
]}

POVEY, AF ^{[1
]}

SHERWOOD, PMA ^{[1
]}

机构：

[1] UNIV NEWCASTLE UPON TYNE,SCH CHEM,NEWCASTLE TYNE NE1 7RU,TYNE & WEAR,ENGLAND

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 98卷 / 01期

关键词：

D O I：

10.1016/S0022-0728(79)80286-7

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The surface of molybdenum metal was examined by XPS after exposure to gaseous and liquid systems and after electrochemical treatment. The latter being conducted in a specially designed electrochemical cell situated in a vacuum chamber attached to the main spectrometer chamber. The results show that a clean molybdenum metal surface is unaffected by oxygen gas and deoxygenated sulphuric acid. It was slightly oxidized by deoxygenated water and appreciably oxidized by oxygenated water. The Mo(VI) oxide is not observed after cathodic polarisation. © 1979 Elsevier Sequoia S.A.

引用

页码：79 / 89

页数：11

共 3 条

[1] X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES OF ELECTRODE SURFACES USING A NEW CONTROLLED TRANSFER TECHNIQUE .1. DESCRIPTION OF APPARATUS AND PRELIMINARY STUDIES [J].

ANSELL, RO ;

DICKINSON, T ;

POVEY, AF ;

SHERWOOD, PMA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1979, 98 (01) :69-77

[2] CORROSION AND PASSIVATION OF THIN MOLYBDENUM FILMS [J].

LEE, LH ;

DOO, VY .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1971, 118 (03) :443-&

[3] ANODIC-DISSOLUTION OF MOLYBDENUM IN ALKALINE-SOLUTIONS - X-RAY PHOTOELECTRON SPECTROSCOPIC STUDIES [J].

POVEY, AF ;

METCALFE, AA .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1977, 84 (01) :73-81

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