AN UNUSUALLY FACILE [3,3]-SIGMATROPIC REARRANGEMENT IN A STEREOSPECIFIC SYNTHESIS OF NOVEL 2',3'-DIDEOXYNUCLEOSIDE PRECURSORS

被引：14
|
作者：
ARMSTRONG, PL
COULL, IC
HEWSON, AT
SLATER, MJ
机构：
[1] SHEFFIELD HALLAM UNIV, DIV CHEM, SHEFFIELD S1 1WB, S YORKSHIRE, ENGLAND
[2] SHEFFIELD HALLAM UNIV, HLTH RES INST, SHEFFIELD S1 1WB, S YORKSHIRE, ENGLAND
[3] WELLCOME RES LABS, BECKENHAM BR3 3BS, KENT, ENGLAND
来源：
TETRAHEDRON LETTERS | 1995年 / 36卷 / 24期
关键词：
D O I：
10.1016/0040-4039(95)00747-Z
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The glycal 5 is converted to intermediates which undergo, under mild conditions, thermal aza-Claisen rearrangements, leading to the amides 7 and 8 and the 2-pyrimidone 9, all potential precursors to 2',3'-dideoxynucleosides.
引用
收藏
页码：4311 / 4314
页数：4
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