FERROCENE-ATTACHED L-LYSINE POLYMERS AS MEDIATORS FOR GLUCOSE-SENSING ELECTRODES

被引：25

作者：

IIJIMA, S ^{[1
]}

MIZUTANI, F ^{[1
]}

YABUKI, S ^{[1
]}

TANAKA, Y ^{[1
]}

ASAI, M ^{[1
]}

KATSURA, T ^{[1
]}

HOSAKA, S ^{[1
]}

IBONAI, M ^{[1
]}

机构：

[1] KOGAKUIN UNIV,FAC ENGN,DEPT IND CHEM,SHINJUKU KU,TOKYO 160,JAPAN

来源：

ANALYTICA CHIMICA ACTA | 1993年 / 281卷 / 03期

关键词：

AMPEROMETRY; BIOSENSORS; ENZYMATIC METHODS; ENZYME ELECTRODES; FERROCENE; GLUCOSE; LYSINE POLYMERS; POLYMERIC MEDIATORS;

D O I：

10.1016/0003-2670(93)85006-6

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

Two kinds of water-soluble polymers having ferrocenyl groups were prepared by the reactions of ferrocenoyl chloride with a homopolymer and a copolymer of L-lysine. The polymers acted as electron mediators between electrodes and the reduced form of glucose oxidase. Amperometric glucose-sensing electrodes were constructed by the simultaneous immobilization of each polymeric mediator and glucose oxidase near the surface of a glassy carbon electrode with a semipermeable membrane. The sensing-electrode using the ferrocene-attached L-lysine homopolymer was usable for the determination of glucose concentrations up to 6 mM.

引用

页码：483 / 487

页数：5

共 18 条

[1] SOME NITROGEN-CONTAINING FERROCENE DERIVATIVES [J].

ACTON, EM ;

SILVERSTEIN, RM .

JOURNAL OF ORGANIC CHEMISTRY, 1959, 24 (10) :1487-1490

[2] ELECTRICAL COMMUNICATION BETWEEN REDOX CENTERS OF GLUCOSE-OXIDASE AND ELECTRODES VIA ELECTROSTATICALLY AND COVALENTLY BOUND REDOX POLYMERS [J].

DEGANI, Y ;

HELLER, A .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (06) :2357-2358

[3] REDOX POLYMER-FILMS CONTAINING ENZYMES .1. A REDOX-CONDUCTING EPOXY CEMENT - SYNTHESIS, CHARACTERIZATION, AND ELECTROCATALYTIC OXIDATION OF HYDROQUINONE [J].

GREGG, BA ;

HELLER, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (15) :5970-5975

[4] CROSS-LINKED REDOX GELS CONTAINING GLUCOSE-OXIDASE FOR AMPEROMETRIC BIOSENSOR APPLICATIONS [J].

GREGG, BA ;

HELLER, A .

ANALYTICAL CHEMISTRY, 1990, 62 (03) :258-263

[5] REDOX POLYMER-FILMS CONTAINING ENZYMES .2. GLUCOSE-OXIDASE CONTAINING ENZYME ELECTRODES [J].

GREGG, BA ;

HELLER, A .

JOURNAL OF PHYSICAL CHEMISTRY, 1991, 95 (15) :5976-5980

[6] AMPEROMETRIC GLUCOSE SENSORS BASED ON FERROCENE-MODIFIED POLY(ETHYLENE OXIDE) AND GLUCOSE-OXIDASE [J].

HALE, PD ;

LAN, HL ;

BOGUSLAVSKY, LI ;

KARAN, HI ;

OKAMOTO, Y ;

SKOTHEIM, TA .

ANALYTICA CHIMICA ACTA, 1991, 251 (1-2) :121-128

[7]

ICHIMURA K, 1984, J POLYM SCI POL CHEM, V22, P281

[8] FERROCENE ATTACHED BOVINE SERUM-ALBUMIN AS A MEDIATOR BETWEEN GLUCOSE-OXIDASE AND AN ELECTRODE [J].

MIZUTANI, F ;

ASAI, M .

DENKI KAGAKU, 1988, 56 (12) :1100-1101

[9] AN ENZYME ELECTRODE FOR L-LACTATE WITH A CHEMICALLY-AMPLIFIED RESPONSE [J].

MIZUTANI, F ;

YAMANAKA, T ;

TANABE, Y ;

TSUDA, K .

ANALYTICA CHIMICA ACTA, 1985, 177 :153-166

[10]

MIZUTANI F, 1989, P MRS INT M ADV MATE, V14, P147

← 1 2 →