Physico-Chemical Properties of Carboxymethyl Cellulose (CMC)/Nanosized Titanium Oxide (TiO2) Gamma Irradiated Composite

被引:0
|
作者
Ali, H. E. [1 ]
Atta, A. [2 ]
Senna, M. M. [1 ]
机构
[1] Natl Ctr Radiat Res & Technol NCRRT, Radiat Chem Dept, Cairo, Egypt
[2] Natl Ctr Radiat Res & Technol NCRRT, Radiat Phys Dept, Cairo, Egypt
来源
ARAB JOURNAL OF NUCLEAR SCIENCES AND APPLICATIONS | 2015年 / 48卷 / 04期
关键词
TiO2; Carboxymethyl cellulose; gamma radiation; nanoparticles;
D O I
暂无
中图分类号
TL [原子能技术]; O571 [原子核物理学];
学科分类号
0827 ; 082701 ;
摘要
In this work, TiO2 nanoparticles were prepared by sol-gel method with or without a stabilizer as such as carboxy methylcellulose (CMC). TiO2 nanoparticles was used to prepare CMC/TiO2 composite. In addition, the prepared CMC/TiO2 composites were irradiated by a dose from 10-30 kGy of gamma irradiation. The properties of the prepared CMC/TiO2 composites were characterized by X-ray diffraction (XRD), transmutation electron microscopy (TEM), thermal gravimetric analysis TGA and UV. The obtained data indicated that the stabilizer (CMC) has a significant effect on the particle size distribution. Values of optical energy band gap Eg decreased from 3 eV for CMC to 2.88 eV for CMC with TiO2 whereas these values were decreased to 2.77 by gamma irradiation at a dose of 30 kGy. In addition, thermal gravimetric analysis (TGA) indicated that the thermal stability properties of CMC were increased by the addition of TiO2 and gamma irradiation.
引用
收藏
页码:44 / 52
页数:9
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