EFFECTS OF REACTION MEDIUM ON GRAFTING OF ACRYLONITRILE ONTO SODIUM-SALT OF PARTIALLY CARBOXYMETHYLATED AMYLOSE

被引:9
作者
PATEL, BK [1 ]
PATEL, CP [1 ]
TRIVEDI, HC [1 ]
VIDYANAGAR, V [1 ]
机构
[1] SARDAR PATEL UNIV,DEPT CHEM,VALLABH VIDYANAGAR 388120,GUJARAT,INDIA
来源
STARCH-STARKE | 1993年 / 45卷 / 02期
关键词
D O I
10.1002/star.19930450210
中图分类号
TS2 [食品工业];
学科分类号
0832 ;
摘要
The grafting of acrylonitrile (AN) onto sodium salt of partially carboxymethylated amylose (Na-PCMA) using ceric ammonium nitrate (CAN) as an initiator has been studied in water/solvent mixtures. The solvents used include methanol, ethanol, propanol, butanol, acetone and carbon tetrachloride. The results have been discussed. The effect of reaction medium on the molecular weight of grafted PAN has also been studied. The chain transfer constants (C(s)) for solvents like methanol, ethanol, propanol, butanol, acetone and carbon tetrachloride have been evaluated at 30-degrees-C by the help of Mayo's equation.
引用
收藏
页码:70 / 72
页数:3
相关论文
共 9 条
[1]   GRAFTING OF POLYACRYLONITRILE TO GRANULAR CORN STARCH [J].
BROCKWAY, CE ;
SEABERG, PA .
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1967, 5 (6PA1) :1313-&
[2]   GRAFTING VINYL MONOMERS ONTO SILK FIBERS .7. GRAFT-COPOLYMERIZATION OF METHYL-METHACRYLATE ONTO SILK USING PEROXYDIPHOSPHATE AS INITIATOR [J].
LENKA, S ;
NAYAK, PL ;
MISHRA, MK .
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1980, 84 (JAN) :183-195
[3]   GRAFTING VINYL MONOMERS ONTO WOOL FIBERS .10. GRAFT-COPOLYMERIZATION OF METHYL-METHACRYLATE ONTO WOOL USING ACETYLACETONATO COMPLEX OF MANGANESE(III) [J].
NAYAK, PL ;
SAHU, G ;
SAMAL, S .
JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1981, A16 (07) :1309-1322
[4]   GRAFTING VINYL MONOMERS ONTO SILK FIBERS .1. GRAFT CO-POLYMERIZATION OF METHYL-METHACRYLATE ONTO SILK BY QUINQUEVALENT VANADIUM IONS [J].
NAYAK, PL ;
LENKA, S ;
PATI, NC .
ANGEWANDTE MAKROMOLEKULARE CHEMIE, 1978, 68 (MAY) :117-129
[5]   MOLECULAR WEIGHTS AND INTRINSIC VISCOSITIES OF SOLUTION POLYMERIZED POLYACRYLONITRILE [J].
ONYON, PF .
JOURNAL OF POLYMER SCIENCE, 1959, 37 (131) :315-317
[6]  
PATEL BK, 1991, J POLYM MATER, V8, P321
[7]  
PATEL JR, 1967, STARKE, V19, P330
[8]   TRIVALENT MANGANESE CHELATE-INITIATED GRAFT-COPOLYMERIZATION OF METHYL-METHACRYLATE ONTO SILK FIBERS [J].
SAMAL, RK ;
SURYANARAYANA, GV ;
DASH, PC ;
PANDA, G ;
DAS, DP ;
NAYAK, MC .
JOURNAL OF APPLIED POLYMER SCIENCE, 1981, 26 (07) :2221-2228
[9]  
SHAH SB, IN PRESS STARCH STAR