Crystal structure of bis(mu(2)-methoxy-kappa O:kappa O)hexamethylbis(mu(2)-triphenylacetato-kappa O:kappa O ')bis(mu(2)-triphenylacetato-kappa O-2,O ':kappa O)dialuminium-dilanthanum toluene tetrasolvate

被引：1

作者：

Vinogradov, Alexander A. ^{[1
]}

Roitershtein, Dmitrii M. ^{[1
,2
]}

Minyaev, Mikhail E. ^{[1
]}

Lyssenko, Konstantin A. ^{[3
]}

Nifant'ev, Ilya E. ^{[1
,4
]}

机构：

[1] Russian Acad Sci, AV Topchiev Inst Petrochem Synth, 29 Leninsky Prospect, Moscow 119991, Russia

[2] Russian Acad Sci, ND Zelinsky Inst Organ Chem, 47 Leninsky Prospect, Moscow 119991, Russia

[3] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, 28 Vavilova Str, Moscow 119991, Russia

[4] Moscow MV Lomonosov State Univ, Chem Dept, 1 Leninskie Gory Str,Bldg 3, Moscow 119991, Russia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2018年 / 74卷

基金：

俄罗斯科学基金会;

关键词：

lanthanum; aluminium; triphenyl-acetate; pi-complex; coordination compound; crystal structure;

D O I：

10.1107/S2056989018015876

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Al2La2(C20H15O2)(4)(CH3)(6)(CH3O)(2)]center dot 4CH(3)C(6)H(5) or [{La(Ph3CCOO)(2)(Me3AlOMe)}(2)]center dot 4CH(3)C(6)H(5), was formed in a reaction between lanthanum tris(tetramethylaluminate) and triphenylacetic acid (1:1) with unintended partial oxidation. The triphenylacetate ligand exhibits mu(2)-kappa O-1:kappa O-1' bridging and mu(2)-kappa O-2,O':kappa O-1 semi-bridging coordination modes, forming a dimeric La-2(mu-OCO)(4) core. The semi-bridging triphenylacetate group provides additional bonding with an La3+ cation via the pi-system of one of its phenyl rings. The trimethylmethoxyaluminate anion, which is coordinated to the La3+ cation by its O atom, displays a rather long La-C-Me bond. Two toluene molecules are each disordered over two orientations about centres of symmetry with site occupancy factors of 0.5. The title compound represents the first example of an Ln(III) complex containing both alkyl alkoxide aluminate and pi-bounded arene fragments.

引用

页码：1790 / +

页数：19

共 34 条

[1] Anwander R., 2002, APPL HOMOGENEOUS CAT, P974
[2] ALKYLATION OF LANTHANIDE ALKOXIDES - SYNTHESIS OF [LN(MU-OBU(T))3(MU-ME)3(ALME2)3] (LN=PR, ND OR Y)
BIAGINI, P
LUGLI, G
ABIS, L
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 474 (1-2) : C16 - C18
[3] Bruker, 2008, APEX2 SAINT SADABS
[4] AMMONIACAL SYNTHESIS OF LANTHANUM ARYLOXIDE COMPLEXES AND OBSERVATION OF A UNIQUE INTERCONVERSION BETWEEN OXYGEN-BRIDGED AND ETA-ARENE-BRIDGED DIMERIC SPECIES - X-RAY CRYSTAL-STRUCTURES OF LA-2(OAR)(6)(NH3)(N) (N=0, 2), LA(OAR)(3)(NH3)(4), AND LA(OAR)(3)(THF)(2) (AR=2,6-I-PR2C6H3)
BUTCHER, RJ
CLARK, DL
GRUMBINE, SK
VINCENTHOLLIS, RL
SCOTT, BL
WATKIN, JG
[J]. INORGANIC CHEMISTRY, 1995, 34 (22) : 5468 - 5476
[5] A simple synthesis and a structural survey of homoleptic rare earth(III) 2,6-diphenylphenolates
Deacon, GB
Feng, TC
Forsyth, CM
Gitlits, A
Hockless, DCR
Qi, S
Skelton, BW
White, AH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2000, (06): : 961 - 966
[6] Utility of 2-methoxyethanol in the synthesis of polyeuropium complexes:: {[Eu(OCH2CH2OMe)2(OC6H3R2-2,6)-][H+]}4 (R = Me, iPr) and [EuAl2(OCH2CH2OMe)3Me5]2
Evans, WJ
Greci, MA
Ziller, JW
[J]. INORGANIC CHEMISTRY, 1998, 37 (20) : 5221 - 5226
[7] NEW COORDINATION ENVIRONMENTS FOR YTTRIUM FORMED IN-SITU BY HETEROMETALLIC BRIDGING - CRYSTAL-STRUCTURES OF (C(5)H(4)SIME(3))Y[(MU-OCME(3))(MU-ME)ALME(2)](2) AND (ME(3)SICH(2))Y[(MU-CH2)(2)SIME(2)][(MU-OR)LI(THF)(2)](2)
EVANS, WJ
BOYLE, TJ
ZILLER, JW
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1993, 462 (1-2) : 141 - 148
[8] REACTIVITY OF Y3(OR)7CL2(THF)2 WITH ORGANOALUMINUM REAGENTS - FORMATION OF THE YTTRIUM ALUMINUM COMPLEXES Y(OR)3(ALME3)3, Y(OR)3(ALME3)2(THF), AND Y(OR)3(ALME2)CL(THF)2 AND THE HALIDES YCL3(DME)2 AND YCL3(THF)3Y3(OR)7O (R = CME3)
EVANS, WJ
BOYLE, TJ
ZILLER, JW
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (12) : 5084 - 5092
[9] Lanthanum(III) chloroaluminate and chlorogallate complexes with toluene and hexamethylbenzene: The effect of arene methylation on the structure
Filatov, Alexander S.
Rogachev, Andrey Yu.
Petrukhina, Marina A.
[J]. JOURNAL OF MOLECULAR STRUCTURE, 2008, 890 (1-3) : 116 - 122
[10] Hexa-μ-chlorido-hexachlorido(η6-hexamethylbenzene)trialuminium(III)lanthanum(III) benzene solvate
Filatov, Alexander S.
Gifford, Sarah N.
Kumar, D. Krishna
Petrukhina, Marina A.
[J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : M286 - U573

← 1 2 3 4 →