DIASTEREOSELECTIVE [4+2] CYCLOADDITIONS OF ACYL NITROSO-COMPOUNDS

被引：75
|
作者：
MARTIN, SF
HARTMANN, M
JOSEY, JA
机构：
[1] Department of Chemistry and Biochemistry, The University of Texas, Austin
来源：
TETRAHEDRON LETTERS | 1992年 / 33卷 / 25期
关键词：
D O I：
10.1016/S0040-4039(00)92508-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A highly diastereoselective route to unsaturated amino alcohol derivatives has been developed that features the [4+2] cycloaddition of chiral acyl nitroso compounds to a variety of conjugated dienes; a useful oxidative method for generating acyl nitroso compounds from the corresponding hydroxamic acids under very mild conditions was also discovered.
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页码：3583 / 3586
页数：4
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