Crystal structure of an organic-inorganic hybrid compound based on morpholinium cations and a beta-type Anderson polyanion

被引：0
|
作者：
Lukianova, Tamara I. [1 ]
Kinzhybalo, Vasyl [1 ]
Pietraszko, Adam [1 ]
机构：
[1] Polish Acad Sci, Inst Low Temp & Struct Res, Okolna Str 2,POB 1410, PL-50950 Wroclaw, Poland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; polyoxidomolybdate; Anderson-type anion; organic-inorganic hybrid;
D O I：
10.1107/S2056989015019246
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
A new organic-inorganic hybrid compound, pentamorpholinium hexahydrogen hexamolybdoferrate(III) sulfate 3.5-hydrate, (C4H10NO)(5)[ Fe-III(OH)(6)Mo6O18]( SO4)center dot 3.5H(2)O, was obtained from an aqueous solution. The polyoxidomolybdate (POM) anion is of the Anderson beta-type with a central Fe-III ion. Three of five crystallographically independent morpholinium cations are disordered over two sets of sites. An intricate network of intermolecular N-H center dot center dot center dot O and O-H center dot center dot center dot O interactions between cations, POMs, sulfate anions and non-coordinating water molecules creates a three-dimensional network structure.
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收藏
页码：1345 / +
页数：19
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