SENSITIVE AND INSENSITIVE REACTIONS ON COPPER CATALYSTS: THE WATER-GAS SHIFT REACTION AND METHANOL SYNTHESIS PROM CARBON DIOXIDE

被引：79

作者：

Chinchen, G. C. ^{[1
]}

Spencer, M. S. ^{[2
]}

机构：

[1] ICI Chem & Polymers Ltd, Catalysis Res Ctr, Billingham TS23 1LB, Cleveland, England

[2] Univ Wales, Coll Cardiff, Sch Chem & Appl Chem, Cardiff CF1 3TB, S Glam, Wales

来源：

CATALYSIS TODAY | 1991年 / 10卷 / 03期

关键词：

D O I：

10.1016/0920-5861(91)80009-X

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The catalytic activity and in situ copper metal areas have been determined for series of Cu/ZnO/Al(2)O(3) catalysts in methanol synthesis from carbon dioxide and in the water-gas shift reaction. Methanol synthesis is an insensitive catalytic reaction, in agreement with our and other previous studies, whereas the water-gas shift reaction is sensitive to catalyst parameters other than copper metal area. This contrast is interpreted in terms of the unified reaction mechanism proposed before.

引用

页码：293 / 301

页数：9

共 37 条

[11] THE ROLE OF COPPER AND ZINC-OXIDE IN METHANOL SYNTHESIS CATALYSTS
BURCH, R
GOLUNSKI, SE
SPENCER, MS
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS, 1990, 86 (15): : 2683 - 2691
[12] SYNERGY BETWEEN COPPER AND ZINC-OXIDE DURING METHANOL SYNTHESIS - TRANSFER OF ACTIVATING SPECIES
BURCH, R
CHAPPELL, RJ
GOLUNSKI, SE
[J]. JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 : 3569 - 3578
[13] THE ROLE OF HYDROGEN IN METHANOL SYNTHESIS OVER COPPER-CATALYSTS
BURCH, R
GOLUNSKI, SE
SPENCER, MS
[J]. CATALYSIS LETTERS, 1990, 5 (01) : 55 - 60
[14] THE ACTIVITY AND STATE OF THE COPPER SURFACE IN METHANOL SYNTHESIS CATALYSTS - COMMENT
CAMPBELL, CT
[J]. APPLIED CATALYSIS, 1987, 32 (1-2): : 367 - 369
[15] CHINCHEN G, IN PRESS
[16] CHINCHEN GC, 1987, SURF SCI, V184, pL370, DOI 10.1016/S0039-6028(87)80264-9
[17] THE ACTIVITY AND STATE OF THE COPPER SURFACE IN METHANOL SYNTHESIS CATALYSTS - REPLY
CHINCHEN, GC
SPENCER, MS
WAUGH, KC
WHAN, DA
[J]. APPLIED CATALYSIS, 1987, 32 (1-2): : 371 - 372
[18] THE MEASUREMENT OF COPPER SURFACE-AREAS BY REACTIVE FRONTAL CHROMATOGRAPHY
CHINCHEN, GC
HAY, CM
VANDERVELL, HD
WAUGH, KC
[J]. JOURNAL OF CATALYSIS, 1987, 103 (01) : 79 - 86
[19] SYNTHESIS OF METHANOL .1. CATALYSTS AND KINETICS
CHINCHEN, GC
DENNY, PJ
JENNINGS, JR
SPENCER, MS
WAUGH, KC
[J]. APPLIED CATALYSIS, 1988, 36 (1-2): : 1 - 65
[20] THE ACTIVITY AND STATE OF THE COPPER SURFACE IN METHANOL SYNTHESIS CATALYSTS
CHINCHEN, GC
WAUGH, KC
WHAN, DA
[J]. APPLIED CATALYSIS, 1986, 25 (1-2): : 101 - 107

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