ENTHALPIC AND ENTROPIC CONTRIBUTIONS TO SUBSTITUENT EFFECTS FOR THE IONIZATION OF META-NITROBENZOIC AND PARA-NITROBENZOIC ACIDS IN WATER-DIMETHYLSULFOXIDE MIXTURES AT 25-DEGREES-C

被引：13

作者：

RODANTE, F

机构：

[1] Istituto di Chimica della Facoltà di Ingegneria, Rome

来源：

THERMOCHIMICA ACTA | 1979年 / 34卷 / 01期

关键词：

D O I：

10.1016/0040-6031(79)80022-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

Enthalpic and entropic contributions to substituent effects for the ionization of m-and p-nitrobenzoic acids are examined, ranging from pure water to 0.8 mole fraction DMSO. The effect of the medium on the substituent and reaction constants is explained in terms of solute-solvent interactions. No structure-breaking effect was found. © 1979.

引用

页码：29 / 34

页数：6

共 24 条

[21] COMPLETE THERMODYNAMIC ANALYSIS OF THE IONIZATION OF ANISIC ACID IN WATER DIMETHYLSULFOXIDE MIXTURES AT 25-DEGREES-C
RODANTE, F
CECCARONI, G
FANTAUZZI, F
THERMOCHIMICA ACTA, 1982, 59 (03) : 253 - 266
[22] Isotopic substitution effects on the volumetric and viscosimetric properties of water-dimethylsulfoxide mixtures at 25 degrees C
Sacco, A
Matteoli, E
JOURNAL OF SOLUTION CHEMISTRY, 1997, 26 (05) : 527 - 535
[23] IONIZATION OF 3 ORGANIC-ACIDS IN METHANOL-WATER MIXTURES AT 25-DEGREES-C
RITZOULIS, G
PAPADOPOULOS, N
HATZIKYRIAKOS, A
JANNAKOUDAKIS, D
ELECTROCHIMICA ACTA, 1984, 29 (06) : 817 - 819
[24] FIRST THERMODYNAMIC DISSOCIATION-CONSTANTS OF 5,5-DISUBSTITUTED BARBITURIC-ACIDS IN WATER AT 25-DEGREES-C .2. STRUCTURE-REACTIVITY RELATIONSHIPS (SRR) - LINEAR FREE-ENERGY RELATIONSHIPS WHICH CORRELATE C(5)-SUBSTITUENT EFFECTS WITH ACID STRENGTH
MCKEOWN, RH
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1980, (03): : 515 - 522

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