FREE-RADICAL POLYMERIZATION OF STYRENE IN DIOCTADECYLDIMETHYLAMMONIUM BROMIDE VESICLES

被引：53

作者：

KURJA, J

NOLTE, RJM

MAXWELL, IA

GERMAN, AL

机构：

[1] EINDHOVEN UNIV TECHNOL,DEPT POLYMER CHEM & TECHNOL,POB 513,5600 MB EINDHOVEN,NETHERLANDS

[2] CATHOLIC UNIV NIJMEGEN,DEPT ORGAN CHEM,6525 ED NIJMEGEN,NETHERLANDS

来源：

POLYMER | 1993年 / 34卷 / 10期

关键词：

VESICLE; DODAB; EMULSION POLYMERIZATION; STYRENE; HOLLOW POLYMER PARTICLE;

D O I：

10.1016/0032-3861(93)90729-T

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The novel radical polymerization of an unsaturated monomer in the hydrophobic part of vesicles is attempted using the experience gathered from kinetic and thermodynamic studies of the emulsion polymerization process. The influence of the monomer content of the system and also the initiation of the polymerization are discussed. A free radical polymerization of styrene in dioctadecyldimethylammonium bromide vesicles is performed. Evidence of the formation of polymer-containing vesicles is obtained by means of electron microscopy and the comparison of the diffusion rate of a paramagnetic probe over the bilayer of vesicles and polymer-containing vesicles.

引用

页码：2045 / 2049

页数：5

共 28 条

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[Anonymous], 1975, CATALYSIS MICELLAR M

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BLACKLEY DC, 1975, EMULSION POLYM

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