HIGHLY SELECTIVE SUPPORTED PD CATALYSTS FOR STEAM REFORMING OF METHANOL

被引:185
|
作者
IWASA, N [1 ]
KUDO, S [1 ]
TAKAHASHI, H [1 ]
MASUDA, S [1 ]
TAKEZAWA, N [1 ]
机构
[1] HOKKAIDO UNIV,DEPT CHEM PROC ENGN,SAPPORO,HOKKAIDO 060,JAPAN
关键词
STEAM REFORMING OF METHANOL; PD/ZNO; SUPPORTED PD CATALYSTS;
D O I
10.1007/BF00771756
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Steam reforming of methanol, CH3OH + H2O --> 3H-2 + CO2, was carried out over various Pd catalysts (Pd/SiO2, Pd/Al2O3, Pd/La2O3, Pd/Nb2O5, Pd/Nd2O3, Pd/ZrO2, Pd/ZnO and unsupported Pd). The reaction was greatly affected by the kind of support. The selectivity for the steam reforming was anomalously high over Pd/ZnO catalysts.
引用
收藏
页码:211 / 216
页数:6
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