HIGHLY SELECTIVE SUPPORTED PD CATALYSTS FOR STEAM REFORMING OF METHANOL

被引：186

作者：

IWASA, N ^{[1
]}

KUDO, S ^{[1
]}

TAKAHASHI, H ^{[1
]}

MASUDA, S ^{[1
]}

TAKEZAWA, N ^{[1
]}

机构：

[1] HOKKAIDO UNIV,DEPT CHEM PROC ENGN,SAPPORO,HOKKAIDO 060,JAPAN

来源：

CATALYSIS LETTERS | 1993年 / 19卷 / 2-3期

关键词：

STEAM REFORMING OF METHANOL; PD/ZNO; SUPPORTED PD CATALYSTS;

D O I：

10.1007/BF00771756

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Steam reforming of methanol, CH3OH + H2O --> 3H-2 + CO2, was carried out over various Pd catalysts (Pd/SiO2, Pd/Al2O3, Pd/La2O3, Pd/Nb2O5, Pd/Nd2O3, Pd/ZrO2, Pd/ZnO and unsupported Pd). The reaction was greatly affected by the kind of support. The selectivity for the steam reforming was anomalously high over Pd/ZnO catalysts.

引用

页码：211 / 216

页数：6

共 11 条

[1] COPPER-CATALYSTS FOR THE STEAM REFORMING OF METHANOL - ANALYSIS OF THE PREPARATION VARIABLES [J].

AGARAS, H ;

CERRELLA, G ;

LABORDE, MA .

APPLIED CATALYSIS, 1988, 45 (01) :53-60

[2]

BARTON J, 1980, COLL CZECH CHEM COMM, V45

[3] HYDROGEN-OXYGEN TITRATION METHOD FOR MEASUREMENT OF SUPPORTED PALLADIUM SURFACE-AREAS [J].

BENSON, JE ;

HWANG, HS ;

BOUDART, M .

JOURNAL OF CATALYSIS, 1973, 30 (01) :146-153

[4] DEHYDROGENATION OF METHANOL TO METHYL FORMATE OVER PALLADIUM ZINC-OXIDE CATALYSTS [J].

IWASA, N ;

YAMAMOTO, O ;

AKAZAWA, T ;

OHYAMA, S ;

TAKEZAWA, N .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (18) :1322-1323

[5]

KASAOKA S, 1980, NENRYO KYOKAI SHI, V59, P40

[6] METHANOL-REFORMING REACTION OVER COPPER-CONTAINING CATALYSTS - THE EFFECTS OF ANIONS AND COPPER LOADING IN THE PREPARATION OF THE CATALYSTS BY KNEADING METHOD [J].

KOBAYASHI, H ;

TAKEZAWA, N ;

MINOCHI, C .

JOURNAL OF CATALYSIS, 1981, 69 (02) :487-494

[7]

LABORDE MA, 1981, LAT AM J CHEM ENG AP, V11, P93

[8] PRODUCTION OF SYNTHESIS GAS WITH VARIOUS COMPOSITIONS OF H2, CO, AND CO2 FROM METHANOL AND WATER ON A NI-K/AL2O3 CATALYST [J].

MIZUNO, K ;

YOSHIKAWA, K ;

WAKEJIMA, N ;

TAKEUCHI, Y ;

WATANABE, A .

CHEMISTRY LETTERS, 1986, (11) :1969-1972

[9] THE MECHANISM OF STEAM REFORMING OF METHANOL OVER A COPPER-SILICA CATALYST [J].

TAKAHASHI, K ;

TAKEZAWA, N ;

KOBAYASHI, H .

APPLIED CATALYSIS, 1982, 2 (06) :363-366

[10] ON THE DIFFERENCE IN REACTION PATHWAYS OF STEAM REFORMING OF METHANOL OVER COPPER-SILICA AND PLATINUM-SILICA CATALYSTS [J].

TAKAHASHI, K ;

KOBAYASHI, H ;

TAKEZAWA, N .

CHEMISTRY LETTERS, 1985, (06) :759-762

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