UPS AND HREELS STUDIES OF EARLY STAGES OF ADSORPTION OF CUCL ON TIO2(110)

被引：5
作者：
WU, MC
MOLLER, PJ
机构：
[1] Department of Physical Chemistry, H.C. Ørsted Institute, University of Copenhagen
来源：
CHEMICAL PHYSICS LETTERS | 1990年 / 171卷 / 1-2期
关键词：
D O I：
10.1016/0009-2614(90)80064-K
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The valence-band electronic structures and vibrational modes of molecular-beam CuCl deposited upon 1 × 1 TiO2(110) surfaces at 293 K have been studied by means of ultraviolet photoelectron spectroscopy (UPS) and high-resolution electron energy-loss spectroscopy (HREELS). Initially, CuCl molecules are adsorbed on the surfaces with the Cu end of the molecule oriented toward the surface. Rehybridization between the adsorbate Cu 3d levels and the substrate O 2p levels occurs. A CuCl vibrational mode is found at 186 cm-1. © 1990.
引用
收藏
页码：136 / 140
页数：5
相关论文
共 50 条
[21]   THE ADSORPTION AND PHOTODESORPTION OF OXYGEN ON THE TIO2(110) SURFACE [J].
LU, GQ ;
LINSEBIGLER, A ;
YATES, JT .
JOURNAL OF CHEMICAL PHYSICS, 1995, 102 (11) :4657-4662
[22]   Local hydroxyl adsorption geometry on TiO2(110) [J].
Unterberger, W. ;
Lerotholi, T. J. ;
Kroeger, E. A. ;
Knight, M. J. ;
Duncan, D. A. ;
Kreikemeyer-Lorenzo, D. ;
Hogan, K. A. ;
Jackson, D. C. ;
Wlodarczyk, R. ;
Sierka, M. ;
Sauer, J. ;
Woodruff, D. P. .
PHYSICAL REVIEW B, 2011, 84 (11)
[23]   NO adsorption and diffusion on hydroxylated rutile TiO2(110) [J].
Yu, Yan-Yan ;
Diebold, Ulrike ;
Gong, Xue-Qing .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2015, 17 (40) :26594-26598
[24]   Adsorption dynamics of water on the surface of TiO2 (110) [J].
Bundaleski, N. ;
Silva, A. G. ;
Schroeder, U. ;
Moutinho, A. M. C. ;
Teodoro, O. M. N. D. .
25TH SUMMER SCHOOL AND INTERNATIONAL SYMPOSIUM ON THE PHYSICS OF IONIZED GASES - SPIG 2010, 2010, 257
[25]   Adsorption of small hydrocarbons on rutile TiO2(110) [J].
Chen, Long ;
Smith, R. Scott ;
Kay, Bruce D. ;
Dohnalek, Zdenek .
SURFACE SCIENCE, 2016, 650 :83-92
[26]   The adsorption of hydrogen on the rutile TiO2(110) surface [J].
Kunat, M ;
Burghaus, U ;
Wöll, C .
PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (16) :4203-4207
[27]   Ultrathin films of CuCl on TiO2(110). Electronic structure and surface reconstruction [J].
Wu, Ming-cheng ;
Guo, Qin-lin ;
Moller, P.J. .
Vacuum, 1990, 41 (4 -6 Pt2) :1418-1421
[28]   Study of the interactions between the overlayer and the substrate in the early stages of palladium growth on TiO2(110) [J].
Della Negra, M ;
Nicolaisen, NM ;
Li, ZS ;
Moller, PJ .
SURFACE SCIENCE, 2003, 540 (01) :117-128
[29]   SURFACE-ADSORPTION PROPERTIES OF GAP (IBARIBARIBAR) STUDIES BY XPS, UPS AND HREELS [J].
XIAO, HY ;
LU, XK ;
DONG, GS ;
DING, XM ;
CHEN, P ;
WANG, X .
PHYSICA SCRIPTA, 1990, 41 (06) :1037-1040
[30]   Adsorption of L-cysteine on rutile TiO2(110) [J].
Ataman, Evren ;
Isvoranu, Cristina ;
Knudsen, Jan ;
Schulte, Karina ;
Andersen, Jesper N. ;
Schnadt, Joachim .
SURFACE SCIENCE, 2011, 605 (1-2) :179-186
12345