THERMAL AND CATALYTIC POLYMERIZATION OF DIETHYNYLDIPHENYLSILANE

被引：52
作者：
BARTON, TJ
IJADIMAGHSOODI, S
PANG, Y
机构：
[1] Ames Laboratory, U.S. Department of Energy, Department of Chemistry, Iowa State University, Ames
来源：
MACROMOLECULES | 1991年 / 24卷 / 06期
关键词：
D O I：
10.1021/ma00006a007
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The thermal polymerization of diethynyldiphenylsilane, reported in 1968 to afford the poly-(silylenebutadiyne), -[Ph2Si-C = C-C = C]n-, has been reinvestigated and found not to produce a polymer containing acetylenic units in the chain. Vastly improved properties are achieved when the polymerization is catalytically induced with MoCl5 or WCl6. These polymers are electrically conducting (10(-3) S/cm) with I2 doping and form good-quality solvent-cast films.
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页码：1257 / 1260
页数：4
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