THERMAL AND CATALYTIC POLYMERIZATION OF DIETHYNYLDIPHENYLSILANE

被引：52

作者：

BARTON, TJ

IJADIMAGHSOODI, S

PANG, Y

机构：

[1] Ames Laboratory, U.S. Department of Energy, Department of Chemistry, Iowa State University, Ames

来源：

MACROMOLECULES | 1991年 / 24卷 / 06期

关键词：

D O I：

10.1021/ma00006a007

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The thermal polymerization of diethynyldiphenylsilane, reported in 1968 to afford the poly-(silylenebutadiyne), -[Ph2Si-C = C-C = C]n-, has been reinvestigated and found not to produce a polymer containing acetylenic units in the chain. Vastly improved properties are achieved when the polymerization is catalytically induced with MoCl5 or WCl6. These polymers are electrically conducting (10(-3) S/cm) with I2 doping and form good-quality solvent-cast films.

引用

页码：1257 / 1260

页数：4

共 9 条

[1] HEXAKIS(TRIMETHYLSILYL)-2-BUTYNE BY TRIMETHYLSILYLATION OF HEXACHLORO-1,3-BUTADIENE [J].