AG-AG+ SYSTEM - IMPEDANCE MODEL FOR NUCLEATION AND GROWTH

被引：43
作者：
CACHET, C
EPELBOIN, I
KEDDAM, M
WIART, R
机构：
[1] Groupe de Recherche no. 4 du C.N.R.S. Physique des Liquides, Electrochimie associé à l'Université Pierre et Marie Curie, 75230 Paris Cedex 05, 4, place Jussieu
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1979年 / 100卷 / 1-2期
关键词：
D O I：
10.1016/S0022-0728(79)80194-1
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
An analytical expression for the electrochemical impedance spectra is calculated, based on the assumption of successive monolayers generated at a mean nucleation rate and governed by the same ageing law. From simulated complex plane impedance plots, it is shown that this model can be applied to highly reversible metal-ion systems such as Ag+⇋Ag. © 1979 Elsevier Sequoia S.A.
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页码：745 / 757
页数：13
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