PR SEPARATIONS OF HYBRID IR BANDS

被引：44

作者：

SETHPAUL, WA

DEMEYER, H

机构：

[1] Janssen Pharmaceutica n.v., Research Laboratories

来源：

JOURNAL OF MOLECULAR STRUCTURE | 1969年 / 3卷 / 1-2期

关键词：

D O I：

10.1016/0022-2860(69)80002-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The PR separation in band envelopes of hybrid bands in vapour-phase ir spectroscopy may be calculated according to the formula: {A figure is presented} where Sα refers to the PR separation of the pure type-α band and α to the angle between the direction of the oscillating dipole and the minor (α) axis of inertia with respect to the other (β) axis. The parameter ≈x is either a number, a constant ratio or a function of several molecular constants depending on the value of x and ρ{variant}*. © 1969.

引用

页码：11 / &

共 23 条

[1] The band envelopes of unsymmetrical rotator molecules. I. Calculation of the theoretical envelopes [J].