FIELD-INDUCED SMECTIC-A TO SMECTIC-C TRANSITION IN FERROELECTRIC LIQUID-CRYSTALS WITH A CHIRAL GROUP ON EACH END OF THE CORE

被引:15
作者
KOBAYASHI, S [1 ]
ISHIBASHI, S [1 ]
机构
[1] NIPPON TELEGRAPH & TEL PUBL CORP, INTERDISCIPLINARY RES LABS, MUSASHINO, TOKYO 180, JAPAN
来源
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1994年 / 257卷
关键词
FERROELECTRIC LIQUID CRYSTAL; ELECTRIC-FIELD-INDUCED PHASE TRANSITION; FIRST-ORDER TRANSITION; SPONTANEOUS POLARIZATION; TILT ANGLE;
D O I
10.1080/10587259408033775
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The smectic A to chiral smectic C transition was studied in dichiral ferroelectric liquid crystals with an optically active alkanoyl group on one end of the core and another chiral group on the other end. Two electric current peaks were observed when a triangular-wave electric field was applied to the dichiral compounds in the smectic A phase. Texture observation and induced tilt angle measurement under an electric field revealed that these two current peaks ale attributable to an electric-field-induced smectic A to smectic C phase transition. Differential scanning calorimetry and spontaneous polarization measurement showed that the smectic A to chiral smectic C transition of the dichiral compounds is first-order. The field-induced transition is attributed to the large spontaneous polarization and the first-order property of the transition.
引用
收藏
页码:181 / 192
页数:12
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