REACTIONS OF MERCURIATED POLYSTYRENES WITH BORON HYDRIDES

被引：5

作者：

ELASSIERY, SA ^{[1
]}

DILLINGHAM, KA ^{[1
]}

PONSONBY, A ^{[1
]}

THORPE, FG ^{[1
]}

WAREHAM, RS ^{[1
]}

机构：

[1] UNIV LANCASTER,SCH PHYS & MAT,CTR POLYMER,LANCASTER LA1 4YA,ENGLAND

来源：

EUROPEAN POLYMER JOURNAL | 1993年 / 29卷 / 2-3期

关键词：

D O I：

10.1016/0014-3057(93)90117-X

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Linear and cross-linked polystyrenes were mercuriated using mercury(II)trifluoracetate in dichloromethane, dioxane, and THF as solvents, and examples of the mercuriated polymers reacted with a range of boron hydrides to give, after hydrolysis, polymers containing boronic acid groups. The extents of mercuriation, and the efficiencies of the transmetallation reaction in which mercury was replaced by boron were compared for different reactants and conditions.

引用

页码：443 / 447

页数：5

共 13 条

[1] PREPARATION OF SUBSTITUTED POLY(VINYLTHIOPHENE)S VIA LITHIATION OF POLY(VINYLTHIOPHENE)
ALKADHUMI, AAH
HODGE, P
THORPE, FG
[J]. POLYMER, 1985, 26 (11) : 1695 - 1700
[2] CHEMICAL MODIFICATION VIA MERCURIATION AND THALLIATION OF CROSS-LINKED POLYMERS PREPARED FROM ACENAPHTHYLENE - PREPARATION OF POLYMERS CONTAINING IODO, PHENOLIC, OR BORONIC ACID RESIDUES
ALKADHUMI, AAHA
HODGE, P
HUNT, BJ
THORPE, FG
[J]. REACTIVE POLYMERS, 1987, 7 (01): : 15 - 23
[3] LITHIATION, MERCURIATION, AND THALLIATION OF POLY(N-VINYLCARBAZOLE) - CHEMICAL-TRANSFORMATIONS OF THE PRODUCTS
ALKADHUMI, AAHA
HODGE, P
THORPE, FG
[J]. BRITISH POLYMER JOURNAL, 1987, 19 (3-4): : 325 - 331
[4] BEVINGTON JC, 1970, MAKROMOLEKUL CHEM, V134, P327
[5] BROWN HC, 1975, ORGANIC SYNTHESES VI
[6] MERCURIATION AND THALLIATION OF POLYSTYRENE - CONVERSION OF THE PRODUCTS INTO POLYSTYRENES CONTAINING IODOBENZENE, PHENYLBORONIC ACID, AND PHENOL RESIDUES
BULLEN, NP
HODGE, P
THORPE, FG
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1981, (07): : 1863 - 1867
[7] USE OF POLYMERS AS PROTECTING GROUPS IN ORGANIC-SYNTHESIS - APPLICATION OF POLYSTYRYLBORONIC ACID TO THE ONE-POT SYNTHESIS OF ACYLATED CARBOHYDRATE-DERIVATIVES
FRECHET, JMJ
NUYENS, LJ
SEYMOUR, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1979, 101 (02) : 432 - 436
[8] LITHIATION OF CROSSLINKED POLYMERS PREPARED USING 2-VINYLTHIOPHEN - APPLICATION TO THE PREPARATION OF POLYMER-SUPPORTED REAGENTS
HODGE, P
LIU, MG
THORPE, FG
[J]. POLYMER, 1990, 31 (01) : 140 - 144
[9] POLYMERIC REAGENTS - POLY(TRIFLUOROACETOXYMERCURIO)STYRENE - PREPARATION AND USE IN REACTIONS WITH ALKYL-HALIDES
HRUDKOVA, H
CEFELIN, P
JANOUT, V
[J]. POLYMER BULLETIN, 1988, 20 (02) : 143 - 148
[10] SEPARATION OF GLYCOLIPIDS FROM NEUTRAL LIPIDS AND PHOSPHOLIPIDS
KROHN, K
EBERLEIN, K
GERCKEN, G
[J]. JOURNAL OF CHROMATOGRAPHY, 1978, 153 (02): : 550 - 552

← 1 2 →