NOVEL PHOTOREACTION OF 4-TRIBROMOMETHYL-4-METHYL-2,5-CYCLOHEXADIENONE WITH AMINE

被引：7
|
作者：
HASEGAWA, E
TAMURA, Y
HORAGUCHI, T
ISOGAI, K
SUZUKI, T
机构：
[1] NIIGATA UNIV,FAC ENGN,DEPT CHEM & CHEM ENGN,NIIGATA 95021,JAPAN
[2] NIIGATA UNIV,GRAD SCH SCI & TECHNOL,NIIGATA 95021,JAPAN
来源：
TETRAHEDRON LETTERS | 1994年 / 35卷 / 46期
关键词：
D O I：
10.1016/S0040-4039(00)78459-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Irradiation of 4-tribromomethyl-4-methyl-2,5-cyclohexadienone in the presence of amines gave 4-bromo-5-methyltropone as a major product. On the basis of the results obtained, the mechanism involving single electron transfer from the amine ground state to the dienone excited state was proposed.
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页码：8643 / 8646
页数：4
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