NOVEL PHOTOREACTION OF 4-TRIBROMOMETHYL-4-METHYL-2,5-CYCLOHEXADIENONE WITH AMINE

被引：7

作者：

HASEGAWA, E

TAMURA, Y

HORAGUCHI, T

ISOGAI, K

SUZUKI, T

机构：

[1] NIIGATA UNIV,FAC ENGN,DEPT CHEM & CHEM ENGN,NIIGATA 95021,JAPAN

[2] NIIGATA UNIV,GRAD SCH SCI & TECHNOL,NIIGATA 95021,JAPAN

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 46期

关键词：

D O I：

10.1016/S0040-4039(00)78459-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Irradiation of 4-tribromomethyl-4-methyl-2,5-cyclohexadienone in the presence of amines gave 4-bromo-5-methyltropone as a major product. On the basis of the results obtained, the mechanism involving single electron transfer from the amine ground state to the dienone excited state was proposed.

引用

页码：8643 / 8646

页数：4

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