(S,S)-BIS-PARA-TOLYLSULFINYLMETHANE AND CARBONYL-COMPOUNDS - REACTIVITY AND ASYMMETRIC INDUCTION

被引：28

作者：

SOLLADIE, G ^{[1
]}

COLOBERT, F ^{[1
]}

RUIZ, P ^{[1
]}

HAMDOUCHI, C ^{[1
]}

CARRENO, MC ^{[1
]}

RUANO, JLG ^{[1
]}

机构：

[1] UNIV AUTONOMA MADRID,DEPT QUIM,E-28049 MADRID,SPAIN

来源：

TETRAHEDRON LETTERS | 1991年 / 32卷 / 30期

关键词：

ASYMMETRIC SYNTHESIS; CHIRAL SULFOXIDES; (S; S)-BIS-P-TOLYLSULFINYLMETHANE; 4-SUBSTITUTED (E,E)-(S,S)-1,1-BIS-(PARA-TOLYL-SULFINYL)-1,3-BUTADIENES;

D O I：

10.1016/S0040-4039(00)79770-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(S,S)-bis p-Tolylsulfinylmethane was shown to react with aromatic aldehydes with a high diastereoselectivity. In contrast, ,beta-unsaturated aldehydes, giving only the elimination products, are in one step transformed into 4-substituted (E,E)-(S,S)-1,1-bis (p-tolylsulfinyl)-1,3-butadiene.

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页码：3695 / 3698

页数：4

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