TRANSITION-METAL COMPLEXES OF 1-(3-HYDROXY-2-NAPHTHOYL)-4-PHENYL-3-THIOSEMICARBAZIDE

被引:0
作者
ABUELREASH, GM
IBRAHIM, KM
BEKHEIT, MM
机构
来源
BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE | 1991年 / 02期
关键词
THIOSEMICARBAZIDE; TRANSITION METALS; COMPLEXES SPECTRA; MAGNETIC MEASUREMENTS;
D O I
暂无
中图分类号
Q5 [生物化学]; Q7 [分子生物学];
学科分类号
071010 ; 081704 ;
摘要
The synthesis and characterization of Cr(III), Fe(III), Mn(II) Co(II), Ni(II), Pd(II), Cu(II), Zn(II), Cd(II) and UO22+ complexes of 1-(3-hydroxy-2-naphthoyl)-4-phenyl-3-thiosemicarbazide (H2NPTS) are reported. IR and NMR spectral data show that the ligand behaves in a tridentate and/or tetradentate manner. An octahedral structure is proposed for the Cr(III), Fe(III), Mn(II), Co(HNPTS)2 and Co(HNPTS)OAc complexes; a square planar structure for the Ni(II), Pd(II) and Cu(II) complexes; and a tetrahedral structure for Co(NPTS) complex.
引用
收藏
页码:149 / 154
页数:6
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