MO-95 NUCLEAR MAGNETIC-RESONANCE AND VIBRATIONAL SPECTROSCOPIC STUDIES OF MOLYBDENUM(VI) SPECIES IN AQUEOUS-SOLUTIONS AND SOLVENT EXTRACTS FROM HYDROCHLORIC AND HYDROBROMIC ACID - EVIDENCE FOR THE COMPLEXES [MO2O5(H2O)6]2+, [MOO2X2(H2O)2] (X = CL OR BR), AND [MOO2CL4]2-

被引：43

作者：

CODDINGTON, JM ^{[1
]}

TAYLOR, MJ ^{[1
]}

机构：

[1] UNIV AUCKLAND,DEPT CHEM,AUCKLAND,NEW ZEALAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1990年 / 01期

关键词：

D O I：

10.1039/dt9900000041

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

引用

页码：41 / 47

页数：7

共 50 条

[1] Synthesis and spectroscopic properties of Mo(VI) complexes with phosphine oxide ligands and the crystal structures of [MoO2X2(OPMe3)2] (X=Cl or Br) and [MoO2Br2{0-C6H4(P(O)Ph2)2}• 2CH2Cl2
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[2] PREPARATION AND CRYSTAL-STRUCTURE OF MOO2CL2(H2O)2.H2O.ET4NCL IN RELATION TO THE NATURE OF THE MOLYBDENUM(VI) SPECIES IN HYDROCHLORIC-ACID SOLUTIONS
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[3] Synthesis, characterization and crystal structures of three new inorganic dinuclear diperoxo complexes of W(VI) and Mo(VI); Rb2{O[WO(O2)2H2O]2}•H2O, Rb2{[MoO(O2)2H2O]2}•H2O and Cs2{O[MoO(O2)2]2}
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[7] A Dihalide-Decahydrate Cluster of [X2(H2O)10]2- in a Supramolecular Architecture of {[Na2(H2O)6(H2O@TMEQ[6])]•2(C6H5NO3)}X2(H2O)10 (TMEQ[6] = α,α′,δ,δ′-Tetramethylcucurbit[6]uril; X = Cl, Br)
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