SYNTHESIS OF PERMETHYLATED CYCLOSILANYL ALKALI-METAL DERIVATIVES

被引：17
作者：
UHLIG, F
GSPALTL, P
TRABI, M
HENGGE, E
机构：
[1] Institut für Anorganische Chemie, T.U. Graz, Stremayrgasse 16
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 493卷 / 1-2期
关键词：
PERMETHYLATED CYCLOSILANES; UNDECAMETHYLCYCLOHEXASILANYLPOTASSIUM; POTASSIUM TERT-BUTYLATE; H-1; SI-29; NMR; GAS CHROMATOGRAPHY MASS SPECTROSCOPY;
D O I：
10.1016/0022-328X(94)05348-F
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A simple way for the preparation of undecamethylcyclohexasilanylalkalimetal compounds is described by the reaction of dodecamethylcyclohexasilane with alkalimetal alcoholats in glyme solvents. Reactions of other cyclosilanes are also discussed. Some reactions of undecamethylcyclohexasilanylpotassium with element-halogen derivates and inorganic acids are described.
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页码：33 / 40
页数：8
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