NONCONJUGATED DIENES FROM 1-ALKENES - APPLICATION TO THE SYNTHESIS OF SEX-PHEROMONE (4E,7Z)-4,7-TRIDECADIENYL ACETATE

被引：9

作者：

KIM, TH

PARK, KM

机构：

[1] Department of Fine Chemical Technology, Chonnam National University, Kwangju

来源：

TETRAHEDRON LETTERS | 1995年 / 36卷 / 27期

关键词：

D O I：

10.1016/0040-4039(95)00905-R

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

(4E,7Z)-4,7-Tridecadienyl acetate 1, a component of the sex pheromone was synthesized from 5-hexenyl acetate. (E)-gamma,delta-Unsaturated phosphonate as the key intermediate afforded a target molecule, using the Homer-Wadsworth-Emmons (HWE) reaction and desulfonylation as the main process.

引用

页码：4833 / 4836

页数：4

共 27 条

[1]

ALEXAKIS A, 1978, TETRAHEDRON LETT, P2027

[2] SUBSTITUTION-REACTIONS OF ORGANOCUPRATES WITH BETA-(PHENYLSELENO)VINYL SULFONES DERIVED FROM THE SELENOSULFONATION OF ACETYLENES - A CONVENIENT AND STEREOSPECIFIC PREPARATION OF VINYL SULFONES AND OLEFINS FROM ACETYLENES [J].