INDENYL EFFECT IN D(0)-TRANSITION METAL-COMPLEXES - SYNTHESIS, MOLECULAR-STRUCTURE AND LACTONE POLYMERIZATION ACTIVITY OF [TI(ETA(5)-C9H7)CL-2(OME)]

被引：26

作者：

OKUDA, J

KONIG, P

RUSHKIN, IL

KANG, HC

MASSA, W

机构：

[1] Fachbereich Chemie der Philipps-Uniuersität Marburg, D-35032 Marburg, Hans-Meerwein-Strasse

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 501卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(95)05590-L

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The titanium methoxo complex Ti(eta(5)-C9H7)Cl-2(OMe), prepared from the trichloro complex Ti(eta(5)-C9H7)Cl-3, was found to polymerize epsilon-caprolactone with ring opening significantly more efficiently than analogous cyclopentadienyl derivatives. The crystal structure of Ti(eta(5)-C9H7)Cl-2(OMe) was determined and shows a C-s-symmetric piano-stool conformation with the strongly pi-donating methoxo group trans to the six-membered ring.

引用

页码：37 / 39

页数：3