Dilithium manganese(II) catena-tetrakis-(polyphosphate), Li2Mn(PO3)(4)

被引：2
作者：
Moutataouia, Meryem [1 ]
Lamire, Mohammed [1 ]
Saadi, Mohamed [2 ]
El Ammari, Lahcen [2 ]
机构：
[1] Fac Sci Ain Chock, Lab Phys Chim Materiaux Inorgan, Casablanca, Morocco
[2] Univ Mohammed V Agdal, Fac Sci, Lab Chim Solide Appliquee, Rabat, Morocco
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
D O I：
10.1107/S1600536813032388
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The poly-phosphate Li2Mn(PO3)(4) was synthesized and its structure characterized from powder diffraction data by Averbuch-Pouchot & Durif [J. Appl. Cryst. (1972), 5, 307-308]. These authors showed that the structure of this phosphate is isotypic to that of Li2Cd(PO3)(4), as confirmed by the present work. The structure is built from infinite zigzag polyphosphate chains, [(PO3)(-)](n), extending along [010]. These polyphosphate chains are connected by sharing vertices with MnO6 octahedra (site symmetry. m.) and Li2O7 polyhedra, which form also chains parallel to [010]. Adjacent chains are linked by common vertices of polyhedra in such a way as to form porous layers parallel to (100). The three-dimensional framework delimits empty channels extending along [010].
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页码：I1 / +
页数：6
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