Crystal structure of bis(4-acetylpyridine-kappa N)bis(ethanol-kappa O)bis(thiocyanato-kappa N)-manganese(II)

被引：0
作者：
Werner, Julia [1 ]
Jess, Inke [1 ]
Naether, Christian [1 ]
机构：
[1] Univ Kiel, Inst Anorgan Chem, Max Eyth Str 2, D-24118 Kiel, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2015年 / 71卷
关键词：
crystal structure; manganese(II); octahedral coordination; hydrogen bonding;
D O I：
10.1107/S2056989015004533
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the crystal structure of the title compound, [Mn(NCS)(2)(C7H7NO)(2)(C2H5OH)(2)], the Mn-II atom is coordinated by two N -bonded thiocyanate anions, two 4-acetyl pyridine ligands, and two ethanol molecules within a slightly distorted octahedron. The asymmetric unit consits of one manganese cation, located on a centre of inversion, one thiocyanate anion, one 4-acetylpyridine ligand and one ethanol molecule in general positions. The discrete complexes are connected by intermolecular O-H center dot center dot center dot O hydrogen bonds between the alcohol OH group and the carbonyl 0 atom into chains parallel to [011].
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收藏
页码：M81 / U77
页数：8
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