WATER-LOSS FROM ESTER MOLECULAR-IONS UPON ELECTRON-IMPACT

被引:6
作者
FOLK, TL
WIDEMAN, LG
COTTMAN, KS
机构
[1] Elastomer and Chemical Research Division, Goodyear Tire & Rubber Co, Akron, Ohio, 44316
来源
ORGANIC MASS SPECTROMETRY | 1979年 / 14卷 / 05期
关键词
D O I
10.1002/oms.1210140510
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
To date, in mass spectral studies of esters, a single reference to loss of water from the molecular ions has been noted. A series of aromatic esters which exhibit that sparsely observed phenomenon are reported herein. Through a combination of synthetic and deuterium labeling studies, support for a unique fragmentation route for the loss of water from these ester molecular ions has been obtained. Copyright © 1979 John Wiley & Sons, Ltd.
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页码:286 / 288
页数:3
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