CALCULATION, SIMULATION AND INTERPRETATION OF ELECTROCHEMICAL IMPEDANCES .3. CONDITIONS FOR OBSERVATION OF LOW-FREQUENCY INDUCTIVE DIAGRAMS FOR A 2-STEP ELECTRON-TRANSFER REACTION WITH AN ADSORBED INTERMEDIATE SPECIES

被引：61

作者：

DIARD, JP

LEGORREC, B

MONTELLA, C

机构：

[1] Ecole Nationale Supérieure d'Electrochimie et d'Electrométallurgie de Grenoble, Centre de Recherche en Electrochimie Minérale et en Génie des Procédés, U.A. C.N.R.S. 1212, 38402 Saint Martin d'Hères

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1992年 / 326卷 / 1-2期

关键词：

D O I：

10.1016/0022-0728(92)80500-4

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

The conditions are determined under which a low frequency inductive arc is observed on the impedance diagrams of an electrode where a reaction consisting of two successive electron transfer steps proceeding by an adsorbed intermediate species is occurring. Impedance zone diagrams make it possible to predict every possible way in which impedance diagrams evolve with the electrode voltage. In particular, sequences comprising low frequency inductive diagrams are studied.

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页码：13 / 36

页数：24

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