SYNTHESIS AND REACTIVITY OF PALLADIUM AND PLATINUM COMPLEXES CONTAINING THE BIS(DIPHENYLPHOSPHINO)METHANIDE LIGAND

被引：19

作者：

FORNIES, J

NAVARRO, R

URRIOLABEITIA, EP

机构：

[1] Departamento de Quimica Inorganica. Instituto de Ciencia de Materiales de Aragon, Universidad de Zaragoza, C.S.I.C.

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 390卷 / 02期

关键词：

D O I：

10.1016/0022-328X(90)85037-Y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes of general formulae [M(C6X5)(Ph2PCHPPh2)(L)] (M Pd, Pt; X F, Cl; L PR3, dppm(Ph2PCH2PPh2)) have been obtained either by reaction of MCl(C6F5)(PR3)2 with dppm and NaH or with dppm-Li or reaction of [M(C6F5)(dppm)(PR3)](ClO4) with NaH. The complexes M(C6X5)(acac)(L) react with dppm to give analogous ddppm {[Ph2PCHPPh2]-} derivatives. Treatment of these complexes with HBF4 gives of the corresponding dppm cationic derivatives. The complexes have been characterized by IR, 19F NMR, and 31P(1H) NMR spectroscopy. © 1990.

引用

页码：257 / 265

页数：9

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