PHOTO-IONIZATION THRESHOLDS OF DIVALENT RARE-EARTH IONS IN ALKALINE-EARTH FLUORIDES

被引:93
作者
PEDRINI, C
MCCLURE, DS
ANDERSON, CH
机构
[1] PRINCETON UNIV,DEPT CHEM,PRINCETON,NJ 08540
[2] RCA LABS,PRINCETON,NJ 08540
关键词
D O I
10.1063/1.437386
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The minimum energy for the onset of photoconductivity has been measured for the ions Ho2+, Dy2+, and Tm2+ in CaF 2, SrF2, and BaF2. This energy is identified with the difference between the impurity level and the bottom of the conduction band. The value of this energy difference is given to within 0.5 eV by a simple electrostatic model including corrections for polarization and for the change of the positions of the ions surrounding the impurity in the crystal. © 1979 American Institute of Physics.
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页码:4959 / 4962
页数:4
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