INCLUSION OF AL(2)ME(6) IN THE CRYSTALLINE LATTICE OF THE ORGANOMETALLIC COMPLEXES LNAL(3)ME(12)

被引：112

作者：

EVANS, WJ

ANWANDER, R

ZILLER, JW

机构：

[1] Department of Chemistry, University of California, Irvine

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 03期

关键词：

D O I：

10.1021/om00003a011

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The homoleptic tetramethylaluminates Ln(AlMe(4))(3) are formed by reaction of excess AlMe(3) in hexane with Ln(NMe(2))(3)(LiCl)(3) obtained from LnCl(3) and LiNMe(2). Nd[(mu-Me)(2)AlMe(2)](3) was characterized by X-ray diffraction, but it was also found that this complex as well as its yttrium analog will cocrystallize with Al(2)Me(6) to form the isostructural alkylaluminum inclusion systems {Ln[(mu-Me)(2)AlMe(2)](3)}(2)[Al(2)Me(6)].

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页码：1107 / 1109

页数：3

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