trans-Bis[4-amino-N-(pyrimidin-2-yl-kappa N) benzenesulfonamidato-kappa N] bis(N, N-dimethylformamide-kappa O) cobalt(II)

被引：3

作者：

Guo, Jing Jing ^{[1
]}

Wang, Wei ^{[1
]}

Zhang, Yi Dong ^{[1
]}

Yang, Li ^{[1
]}

Zhang, Shu Hua ^{[1
]}

机构：

[1] Guilin Univ Technol, Coll Chem & Bioengn, Guilin 541004, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

基金：

中国国家自然科学基金;

关键词：

data-to-parameter ratio = 15.7; disorder in main residue; mean ̄(C-C) = 0.004 Å; R factor = 0.040; single-crystal X-ray study; T = 298 K; wR factor = 0.095;

D O I：

10.1107/S160053681204336X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title complex, [Co(C10H9N4O2S)(2)(C3H7NO)(2)], lies across an inversion center. The Co-II atom is coordinated in a slightly distorted octahedral geometry by four N atoms from two bidentate 4-amino-N-(pyrimidin-2-yl) benzenesulfonamidate (sulfadiazine) anions and two O atoms from two dimethylformamide (DMF) ligands. The dihedral angle between the benzene and pyrimidine rings is 82.37 (13)degrees. A three-dimensional network is generated by N-H center dot center dot center dot O hydrogen bonds between the amino groups and of the sulfonamidate O atoms of neighbouring molecules. The DMF ligand is disordered over two sets of sites in a 0.559 (4):0.441 (4) ratio.

引用

页码：M1398 / +

页数：10

共 9 条

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