CHARACTERIZATION OF DEHYDROCHLORINATED POLY(VINYLIDENE CHLORIDE) AND THE SHOCK-COMPRESSED MATERIAL

被引：11

作者：

KOMATSU, T

NOMURA, M

KAKUDATE, Y

FUJIWARA, S

HEIMANN, RB

机构：

[1] NATL INST MAT & CHEM RES, TSUKUBA, IBARAKI 305, JAPAN

[2] FREIBERG UNIV MIN & TECHNOL, CHAIR TECH MINERAL, D-09596 FREIBERG, GERMANY

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 1995年 / 196卷 / 09期

关键词：

D O I：

10.1002/macp.1995.021960925

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Dehydrochlorinated poly(vinylidene chloride) proved to be a conjugated polyene-polyene polymer. Shock compression of the polymer formed a large portion of graphite and trace amounts of diamond and of an unknown carbon. The unknown carbon belongs to the hexagonal crystal system and possesses the cell dimension a(0) = 0.338 nm. A comparison with known carbynes was made in terms of the crystalline parameters.

引用

页码：3031 / 3040

页数：10

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